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Appendix 18


REVIEW OF MDF PLANT - FORMALDEHYDE AIR DISPERSION, FOR AUSTRALIAN WOOD PANELS ASSOCIATION, EML REPORT 79365, MAY 2006

prepared for

NICNAS


(National Industrial Chemicals Notification and Assessment Scheme)
by

M.F. Hibberd & M. E. Cope CSIRO Marine and Atmospheric Research

Private Bag 1

Aspendale Vic 3195


tel: (03) 9239 4545

fax: (03) 9239 4444

email: mark.hibberd@csiro.au

August 2006

Summary
The modelling in the EML report appears to provide a good description of the configuration of the sources of formaldehyde emissions at a large MDF plant. The use of stack test measurements to determine stack emissions is appropriate. However the method of estimating fugitive emissions is subject to large uncertainties. This is a critical issue because the 24-hour average predicted environmental concentrations (PECs) are significant compared to EPA design criteria and are the largest identified in the NICNAS report. The large uncertainty in the fugitive emissions is due the large uncertainties inherent in the NPI total emissions estimates and to the fact that the fugitive emissions are only a small fraction of the total formaldehyde emissions. For example, allowing for an uncertainty of 5% in the NPI total could reduce the fugitive emission estimate to zero or more than double it to 2,500 kg p.a. The latter case would produce a maximum 24-hour average PEC of 79 ppb, compared to 37 ppb estimated in the EML report. Reducing the uncertainty in the fugitive emission estimate is not straightforward. A possible method would be to measure/estimate the volume flows and formaldehyde concentrations of the fugitive emissions from the building ridge vent and doors.
The review comments on and provides suggestions on a range of issues in the EML report relating to the estimates of formaldehyde PECs for a large MDF plant.


  1. Introduction

This is a review for NICNAS of the EML report for the Australian Wood Panels Association titled MDF Plant, Formaldehyde Air Dispersion, May 2006, (Report No 79365).


The EML report addresses the issue of refining PEC results for the largest formaldehyde emitter identified in the NICNAS report for wood and paper manufacturing industries. The impacts of formaldehyde emissions from such a plant are modelled to determine the predicted environmental concentrations (PECs). These PECs are presented as an update to those presented in an earlier CSIRO report.
The CSIRO report (Formaldehyde Air Quality Assessment, May 2004) had assumed that 50% of the emissions from such a plant were released from a 30 m stack and 50% were fugitive emissions which were treated as a volume source centred at a height of 10 m. This simple configuration was “based on the source descriptions in the NICNAS report”. The CSIRO report noted that “A detailed analysis would require details of the source characteristics for each facility in the NPI database, which is beyond the scope of this study.” The results obtained for wood and paper product manufacturers concluded that “Given the high PECs, it would be appropriate to verify these predictions by obtaining more information about source configurations for these [Wood and Paper] industries.” This is the issue addressed by the EML report.
The results from the EML modelling are reproduced in Table A18-1.
Table A18-1: Predicted environmental concentrations (PECs) in the EML report
Largest Emitter


Annual average PEC

Maximum 24-hour avg PEC


CSIRO assumed default source configuration 0.43 g/s [13,500 kg p.a.] emissions from 30 m stack0.43 g/s [13,500 kg p.a.] emissions from volume source

15 ppb 122 ppb





EML typical facility layout 0.823 g/s emissions from eight stacks

0.015 g/s emissions as volume source from doors 0.022 g/s emissions as volume source from roof ridge modelling includes building wake effects

2 ppb 37 ppb

EML typical facility layout only stack emissions 1 ppb 33 ppb


EML typical facility layout only fugitive emissions 1 ppb 37 ppb

  1. Modelling approach in EML report

The improved modelling approach in the EML report is to use:



  1. a site layout that is more typical of an MDF products plant;

  2. emissions proportioned to reflect typical stack source emission test results; and

  3. estimated levels of fugitive emissions that are the difference between those accounted for from stack source tests and the total NPI emission estimates.

We consider that the first two points are basically sound. However, there is a major problem in the modelling because of uncertainty in the estimate of fugitive emissions derived using the method given in point (iii).



  1. Specify the plant being modelled

The issue addressed in the EML report is the PEC results for the largest emitter in the wood and paper manufacturing industries. A more detailed study could consider the configurations of all large formaldehyde emitters in the wood and paper manufacturing industries, but the methodology adopted in the NICNAS report is to consider the largest emitter. Because NPI estimates and stack test results are used to determine the fugitive emissions, it is essential that both be for the same plant. Although it is inferred that this was done in the EML report, it is not explicitly stated that this was the case. This needs to be clarified.


The NPI database indicates that the largest emitter referred to in the NICNAS report reported formaldehyde emissions of 27,082 kg p.a. in the 2001 – 2002 reporting year. This facility reported similar emissions in the following two years: 27,134 kg in 2002- 2003; and 26,718 kg in 2003-2004. This indicates that the value used in the model was indicative.




  1. Uncertainties in the fugitive emission estimate

Because the fugitive emission estimate (≈1000 kg p.a.) is determined as the difference between two large numbers (27,000 and 25,950), it is critical that the impact of uncertainty in these large numbers be taken into account in the calculation. The EML report does not include any uncertainty estimates. [Note that the EML report uses both kg



    1. and g/sec emission estimates; rounding errors in the conversion produce small differences when comparing the numerical values estimated in different units.] Uncertainties in the estimate of the magnitude of fugitive emissions arise from (in approximate order of importance):

      1. uncertainty in the NPI estimate of total formaldehyde emissions;

      2. uncertainty in the total stack emission rates derived from the stack testing on up to 16 separate stacks;

      3. uncertainty due to differences in the production rate assumed for the NPI estimates and that prevailing at the time the stack testing was undertaken.



  1. Uncertainty in NPI estimates

As mentioned in the EML report, the degree of certainty of the emission factors used in the NPI estimate of 27,000 kg p.a. has been identified as D (below average) or E (poor), see NPI Emission Estimation Technique Manual for Timber and Wood Product

Manufacturing, 11 January 2002, Version 1.1. Although uncertainty estimates are not

given in the manual, it would appear reasonable to conclude that these descriptors correspond to an uncertainty of at least 20% in the NPI estimates (i.e. 27,000 ± 5,400 kg p.a.). In the estimate below, we consider the impact of uncertainties of 20%, 10% and 5% in the NPI estimate.




  1. Uncertainty in total stack emission rate

The uncertainty in the total stack emissions testing involving measurements on up to 16 separate stacks is likely to be much smaller than that in the NPI estimate; a guesstimate is 5%. However, in the absence of more detailed information and the large uncertainty in the

NPI estimate, we ignore this uncertainty in estimating the uncertainty in the fugitive emission rate.




  1. Uncertainty due to differences in the production rate

No information is available to make an estimate of the uncertainty due to differences in the production rate assumed for the NPI estimates and that prevailing at the time the stack testing was undertaken. Thus we also ignore this uncertainty in estimating the uncertainty

in the fugitive emission rate.

The EML report determined the fugitive emission rate to be 0.037 g/sec. This is equal to 1170 kg p.a. Taking into account possible uncertainties of 20%, 10% and 5% in the NPI total emission rate would give the following averages and range of values for the fugitive emissions:


    • 1170 kg p.a. (range 0 – 6600 kg p.a.) for 20% uncertainty in NPI estimate

    • 1170 kg p.a. (range 0 – 3900 kg p.a.) for 10% uncertainty in NPI estimate

    • 1170 kg p.a. (range 0 – 2500 kg p.a.) for 5% uncertainty in NPI estimate.

These indicate that even a 5% uncertainty in the NPI estimate could more than double the fugitive emissions. Scaling the PEC results in Table 18A-1 produces the following range of maximum 24-hour average PECs:



    • 0 kg p.a. fugitives 33 ppb (only stack impact)

    • 2,500 kg p.a. fugitives 79 ppb

That is, the model results are very sensitive to uncertainties in the NPI estimate. Because the 24-hour average PECs are significant compared to NEPM Air Toxics formaldehyde investigation level (40 ppb, 24-hour average) and are the largest identified in the NICNAS report, further work is needed to reduce the uncertainty in the fugitive emission estimate.



  1. Possible method for reducing uncertainty in fugitive estimate

It is very difficult to see how to reduce the uncertainty in the fugitive emission estimate computed as the difference between the NPI estimated total emissions and the measured stack total.

The alternative is to use some other method for estimating fugitive emissions, for example to measure/estimate volume flows (air exchange rates) and 24-hour average formaldehyde concentrations in the fugitive emissions from the roof ridge and doors.

  1. Justification for 40:60 split of fugitives between door:roof ridge

No justification is provided for using a 40%:60% split of the fugitive emissions between the door and roof ridge. Is this important? This could be determined by looking at the sensitivity of the PEC estimates to changes in this split?



  1. Ausplume Modelling

We consider that the set-up of the model, the inclusion of buildings, stacks and fugitive sources is appropriate.

The 24-hour average PECs were calculated on a radial grid at 5º increments and at spacings from 100 m to 1000 m at 100 m increments. This is considered to be suitable for determining the maximum 24-hour average PEC.

However, the annual average concentrations were only determined at a single discrete receptor, which was located 100 m east of the main plant building. This is indicated by

the data listed in Attachment 3 (Air Dispersion Model Outputs). Although this may be the location of the highest annual average PEC for the current fugitive/stack emission characteristics it is possible that this point of maximum concentration will change for other configurations. The annual average PECs should be calculated on the same grid as that used for the 24-hour averages.
The EML Ausplume modelling used a 1997/1998 meteorological file for Paisley in the west of Melbourne. This is the same as that used by CSIRO. Although meteorology from this site was appropriate for the CSIRO assessment of the impact of emissions from a wide range of industries as well as urban and roadway sources, it is recommended that for modelling the impact of the largest formaldehyde emitter (in the wood and paper manufacturing industries), it would be more appropriate to use a local meteorological file (either from measurements or generated by TAPM) for the site of the largest emitter.

  1. Other comments

The end of Section 2 of the EML report lists a number of observations, which it is suggested indicate “that the modelling by CSIRO for NICNAS has generally over- predicted ground-level concentrations of formaldehyde at the boundary of wood product industries, particularly in the case of the largest emitters”. We list these observations and provide our response to each.




  • EML report: Typical Australian State EPA dispersed design criteria for formaldehyde as 3-minute average < 33 ppb or 1-hour average 18 ppb, which would be substantially lower if modelled at the longer averaging period of 24-hours and annual.

CSIRO response: The implication of including this statement is that all plants meet current EPA design criteria. However, even the modelling in the EML report indicates that emissions from the stacks alone (ignoring the contribution from fugitives) produce 24-hour average PECs up to 33 ppb at a distance of 100 m from the source. This is substantially larger than the 18 ppb 1-hour average listed as an EPA criterion. It is modelling and measurements that are relevant for determining PECs, not current standards.




    • EML report: Fugitive emissions concentrations are predominantly reflected by measurement of workplace exposure. The wood panels industry has data indicating that most workplaces are < 20 ppb (8-hour average). At the perimeter, 100 m from the sources of these fugitive concentrations, the ambient concentration on a 24-hour and annual average will be much lower.

CSIRO response: The NICNAS analysis is concerned with maximum values, not typical values. What would be relevant here is the maximum workplace exposure, not readings

from “most workplaces”. Furthermore, the relevance of workplace exposure measurements to the concentration in the fugitive emissions depends on the ventilation arrangements in the facility. Ventilation systems are generally designed to minimise workplace exposure, for example by drawing fresh air in around the workspace and

exhausting it through roof vents. Thus measurements of workplace concentration could be

far lower than concentrations in fugitive exhaust air.




    • EML report: Ambient measurements at the boundary of two wood panel facilities in Australia have reported <10 ppb 24-hour averages.”

CSIRO response: The NICNAS analysis is concerned with maximum values, not typical values. Were these measurements made downwind of the largest emitter? Were the

measurements made under conditions when the maximum 24-hour averages could be



expected to occur? Without further information, such data are not relevant to maximum 24-hour average PECs.



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