Title: Soviet Electrochemistry

Title: Soviet Electrochemistry

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JCR Abbreviated Title: Sov Electrochem Engl Tr

ISSN: 0038-5387

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? Vyaertniu, M.G., Petyarv, E.K. and Palm, U.V. (1975), Isotherm for rubidium ion adsorption on bismuth from methanolic solutions of constant ionic-strength. Soviet Electrochemistry, 11 (3), 449-451.

? Afanasev, B.N., Damaskin, B.B., Avilova, G.I. and Borisova, N.A. (1975), Adsorption-isotherm corresponding to generalized surface-layer model. Soviet Electrochemistry, 11 (4), 548-551.

? Batrakov, V.V. and Damaskin, B.B. (1975), Effect of Uniform Surface Inhomogeneity on Frumkin Isotherm. Soviet Electrochemistry, 11 (6), 882-885.

? Yuzbekov, Y.A., Tedoradze, G.A. and Gadiev, N.K. (1975), Use of impedance measurements for calculating adsorption parameters of organic-substances. 3. Adsorption-kinetics of amyl alcohol on mercury - calculation of amyl alcohol surface concentration by a new method. Soviet Electrochemistry, 11 (6), 897-900.

? Avilova, G.I. and Afansev, B.N. (1975), Adsorption of phenol on a dropping mercury-electrode and its influence on kinetics of electroreduction of V³⁺. Soviet Electrochemistry, 11 (8), 1131-1133.

? Popova, T.I., Timofeeva, L.Z., Simonova, N.A. and Bardina, N.G. (1975), Effect of fluoride-ion adsorption on dissolution kinetics of passive gallium. Soviet Electrochemistry, 11 (9), 1344-1346.

? Podlovchenko, B.I., Kolyadko, E.A. and Menyailova, M.V. (1975), Electrochemical measurements in hydrofluoric-acid solutions at metals of platinum group. 9. Kinetics of propane adsorption and electrooxidation on a platinized platinum-electrode. Soviet Electrochemistry, 11 (9), 1248-1251.

? Shimonis, I.V. (1976), Link between adsorption of solution components and kinetics of processes in hydrochloric-acid solutions. Soviet Electrochemistry, 12 (1), 122-124.

? Tedoradze, G.A., Yuzbekov, Y.A. and Gadiev, N.K. (1976), Use of impedance measurements to calculate adsorption parameters of organic-substances. 5. Adsorption-kinetics of ethyl butyrate on mercury - calculation of adsorption parameters of ethyl butyrate by a new method. Soviet Electrochemistry, 12 (3), 406-410.

? Shimonis, I.V. (1976), Oxygen-adsorption kinetics on platinum in concentrated hydrochloric-acid solutions. Soviet Electrochemistry, 12 (7), 147-1044.

? Afanasev, B.N. (1976), Effect of adsorption potentials on kinetics of electrochemical reactions. Soviet Electrochemistry, 12 (9), 1347-1350.

? Loshkarev, Y.M., Malaya, R.V., Grigorev, N.B. and Kuprin, V.P. (1977), Adsorption processes and cadmium electrodeposition kinetics in relation to association effects of organic inhibitors. Soviet Electrochemistry, 13 (2), 242-244.

? Damaskin, B.B. and Afanasev, B.N. (1977), Current state of theory describing effect of adsorption of organic-substances on electrochemical reaction-kinetics. Soviet Electrochemistry, 13 (8), 939-954.

? Ershler, A.B. and Zvyagintsev, A.M. (1977), Effect of adsorption of 5-bromo-2-acetylthiophene on kinetics of its electrochemical reduction in an acidic medium. Soviet Electrochemistry, 13 (8), 1000-1006.

? Gurina, G.P., Kats, M.Y., Tedoradze, G.A., Feoktistov, L.G. and Gavlin, A.G. (1977), Adsorption-isotherm of dicyanoethylmercury on mercury from an aqueous-solution and dependence of its parameters on potential. Soviet Electrochemistry, 13 (10), 1306-1311.

? Podgaetskii, E.M. (1978), Thermodynamic form of the adsorption-isotherm equation. Soviet Electrochemistry, 14 (5), 685-688.

? Gurevich, Y.Y. and Kharkats, Y.I. (1978), Temperature behavior of adsorption as described by the generalized Frumkin isotherm. Soviet Electrochemistry, 14 (6), 709-712.

? Kicheev, A.G. Bolshikh, A.E. (1978), Oxygen-adsorption kinetics on silver electrodes in alkaline electrolyte. Soviet Electrochemistry, 14 (7), 967-970.

? Grachev, D.K. (1978), Formation of adsorption layers and multilayer films during the anodic-oxidation of cadmium in alkali solutions - kinetics of irreversible oxide adsorption. Soviet Electrochemistry, 14 (12), 1587-1591.

? Grachev, D.K. (1978), Formation of adsorption layers and multilayer films during the anodic-oxidation of cadmium in alkali solutions - kinetics of multilayer oxide film growth. Soviet Electrochemistry, 14 (12), 1624-1627.

? Timashev, S.F. (1979), Effect of the adsorption of surface-active materials on electrochemical reaction-kinetics. Soviet Electrochemistry, 15 (3), 280-285.

? Novoselskii, I.M. (1979), Adsorption-isotherms of hydrogen on a pt electrode - application of the Honig isotherm to a quantitative description of the adsorption of H-atoms on a pt electrode in H₂SO₄ solutions. Soviet Electrochemistry, 15 (4), 396-400.

? Novoselskii, I.M. (1979), Adsorption-isotherm of hydrogen on pt electrodes - rationalization of the adsorption-isotherm on Pt electrodes in H₂SO₄ solutions. Soviet Electrochemistry, 15 (5), 579-581.

? Kiryanov, V.A. (1979), Theory of the Esin-Markov effect - ionic adsorption-isotherm including electric-field penetration into the metal. Soviet Electrochemistry, 15 (5), 655-656.

? Fainerman, V.B. and Yamilova, V.D. (1979), Adsorption-kinetics from solutions at interfaces with gases and liquids. Soviet Electrochemistry, 15 (7), 923-926.

? Novoselskii, I.M. (1979), Hydrogen adsorption-isotherm on platinum-electrodes the entropy and enthalpy of adsorbed H-atoms and the heat of hydrogen adsorption on pt electrodes in H₂SO₄ solutions. Soviet Electrochemistry, 15 (9), 1113-1117.

? Kiryanov, V.A. (1979), Effect of the adsorption of organic-substances on electrochemical reaction-kinetics. Soviet Electrochemistry, 15 (9), 1215-1219.

? Kiryanov, V.A. (1979), Effect of the adsorption of organic-substances on the elementary act of electrochemical reactions and on electrode- reaction kinetics. Soviet Electrochemistry, 15 (9), 1219-1220.

? Podgaetskii, E.M. (1979), Construction of adsorption-isotherm fragments from the theta vs t dependence. Soviet Electrochemistry, 15 (10), 1323-1326.

? Kiryanov, V.A. and Krylov, V.S. (1979), The effect of ionic adsorption on electrochemical reaction- kinetics. Soviet Electrochemistry, 15 (11), 1387-1390.

? Krylov, V.S., Kiryanov, V.A. and Fishtik, I.F. (1980), Effect of the specific adsorption of ions in electrode kinetics. Soviet Electrochemistry, 16 (3), 290-296.

? Fishtik, I.F., Kiryanov, V.A. and Krylov, V.S. (1980), Theory of the effect of adsorption of organic-substances on electrode-kinetics. Soviet Electrochemistry, 16 (3), 354-356.

? Vigdorovich, V.I. and Tsygankova, L.E. (1976), Use of temkin isotherm for an analysis of mechanism of anodic iron dissolution. Soviet Electrochemistry, 19 (9), 1306-1311.

? Dobrenkov, G.A., Guseva, L.T. and Arkhireev, V.E. (1984), Selection of parameters in the equation of the adsorption-isotherm of polyethylene-glycol on a mercury-electrode. Soviet Electrochemistry, 20 (3), 338-340.

? Damaskin, B.B., Safonov, V.A. and Dyatkina, S.L. (1986), Fitting of experimental adsorption data to the Frumkin isotherm. Soviet Electrochemistry, 22 (3), 282-288.

? Gorichev, I.G., Batrakov, V.V. and Damaskin, B.B. (1989), Isotherm selection for ionic adsorption on oxides. Soviet Electrochemistry, 25 (6), 725-728.

Tyurin, Y.M., Chumakov, I.V., Tikhomirov, A.V., Tomilov, A.P. and Smirnova, L.A. (1991), Acrylonitrile adsorption and electroreduction at cadmium in potassium hydrogen phosphate solutions. Soviet Electrochemistry, 27 (4), 406-411.

Abstract: Voltammetry, chronopotentiometry, differential-capacitance and Rehbinder hardness measurements were used to investigate the kinetics of acrylonitrile electroreduction and the adsorption of acrylonitrile at cadmium in 0.005 to 0.05 M K₂HPO₄. An irreversible reduction peak of diffusional origin and a corresponding potential arrest were found. The kinetic parameters were calculated. It was shown that acrylonitrile adsorption is satisfactorily described by the Frumkin isotherm. Certain adsorption parameters as well as the degree of coverage of the electrode surface in the electroreduction region were estimated. The results were compared with literature data for the mercury electrode, and analyzed along the lines of approach developed for describing the kinetics of electroreduction of organic substances in the adsorbed state.