Sublimation (or deposition) curve – the curve on a phase diagram which represents the transition between gaseous and solid states. It represents the effect of increased temperature on a solid at a very low constant pressure, lower than the triple point.
C. Two Important Points
C. Two Important Points
There are two important points on the diagram, the triple point and the critical point.
The triple point
The triple point
The triple point is the combination of pressure and temperature at which all three phases of matter are at equilibrium. It is the point on a phase diagram at which the three states of matter coexist. The lines that represent the conditions of solid-liquid, liquid-vapor, and solid-vapor equilibrium meet at the triple point.
The critical point
The critical point
The critical point terminates the liquid/gas phase line. It is the set of temperature and pressure on a phase diagram where the liquid and gaseous phases of a substance merge together into a single phase. Beyond the temperature of the critical point, the merged single phase is known as a supercritical fluid.
The critical point
The critical point
The temperature and pressure corresponding to this are known as the critical temperature and critical pressure.
If the pressure on a gas (vapor) is increased at a temperature lower than the critical temperature, the liquid-vapor equilibrium line will eventually be crossed and the vapor will condense to give a liquid.
How is the normal melting and boiling points determined in a phase diagram?
How is the normal melting and boiling points determined in a phase diagram?
The normal melting and boiling points are those when the pressure is 1 atmosphere.