Limonene in Australia is either used by the manufacturer and/or importer and/or supplied to formulators to produce intermediate or end products. A similar pattern exists for imported products containing limonene. The distribution chains vary as repacking and reselling may occur as intermediate steps. This is seen with both limonene and products containing limonene, either locally manufactured or imported. The distribution chains of manufactured and/or imported limonene are shown in Figure 1. Figure 2 shows the distribution chains of imported products containing limonene.
7.5Uses
Information on uses of limonene and products containing limonene was provided by industry and also obtained by the NICNAS phone survey. The survey attempted to reach users of limonene through the distribution chain. The formulators and end users were selected randomly, covering a wide range of industry sectors, from customer lists provided by importers and manufacturers. However, the profile of users contacted during the survey might not be representative as only a small proportion of formulators and users of limonene were contacted.
7.5.1Use of limonene
d-Limonene and dipentene may be formulated into intermediate or end products, or used as they are.
Figure 1. Distribution chain of manufactured/imported limonene
x= Repacking is possible
Figure 2. Distribution chain of imported limonene products
x= Repacking is possible
d-Limonene and dipentene are mainly used in the formulation of a range of fragrance or flavour blends that are used to further formulate end products for industry and consumer use or as food additives. Some of the d-limonene and dipentene are used to formulate end products directly. Information provided by importers indicates that d-Limonene and dipentene are both used in the formulation of the following products:
as replacement for toxic chlorinated solvents or as solvent carriers;
flavour and fragrance additives;
essential oils;
wetting and dispersing agents;
resins and specialty adhesives;
cleaners for floor, printing inks and press, spot and stain, metal, marine vessels electronics, circuit board, and concrete;
hand cleaners;
personal or air deodorants;
masking agents for rubbish tips.
d-Limonene is also used as a heat transfer medium; release agent; in asphalt grading; and in graffiti, adhesive, tar and asphalt removers and in the production of degreaser/grease trap maintainer to help dissolve grease and keep foul odours down in grease traps.
It was reported that there is a decreasing trend in formulating perfume products using limonene. The major reason is claimed to be the efficient automated process used overseas which is too high cost for the small market in Australia.
Some d-Limonene and dipentene are used directly for the following industrial purposes:
degreasing agent as liquid or aerosol;
glass mould cleaning;
polystyrene recycling (stripping) and rubber stripping;
air craft part cleaning;
as an adhesive agent in rubber treatment;
wax remover from laboratory slides prior to mounting and for removing hard depilatory wax from floor and instruments in salons;
cleaning tanks with viscous residues;
microbiological and gemstone testing.
Uses of high dipentene grade of pine oil in Australia are reported to be as a solvent for paints, wool, cleaning compounds, disinfectants and polishing solutions.
A small quantity of limonene (type of limonene not specified) is used in laboratories for testing for quality control and as a general laboratory reagent.
Availability of limonene to the general public was not reported.
7.5.2Use of industrial products containing limonene
Both imported and formulated products containing limonene are used either directly or further formulated into products for end use. They have a wide range of applications in Australia.
d-Limonene
Hand cleaners used in workshops
The largest use of products containing d-limonene in industry is as heavy-duty hand cleaners. They are used widely in industrial workshops in Australia. Information obtained from suppliers and the NICNAS industry phone survey indicates that the concentration of d-limonene ranges from 2% to 35%. The package sizes and types vary largely between different manufacturers, but in most cases, the package sizes range from 70 g to 200 kg and package types can be soft tube with a screw cap, plastic bottles with a cap or pump dispenser, steel tin with a cap or lid, and pumps and wall bracket. The quantities and number of formulations obtained during the survey are not representative due to the small survey size.
Industrial cleaning
Industrial cleaning products containing d-limonene have a wide range of applications and concentration of d-limonene varies largely. Information on uses, concentrations of d-limonene and package sizes is listed in the Table 7.3.
Table7.3 - Use of products containing d-limonene in industrial cleaning
-
Uses
|
% d-limonene
|
Package size
|
General degreasing and general purpose cleaning of equipment, floor and oven in various industry sectors such as mining, automotive, hospitality, marine and aircraft industry
|
< 1 - > 60
|
Varies
|
Cleaning of printing press to wash out printing inks
|
5 - 35
|
20 L, 25 L and 200 L steel drums
|
Industrial metal cleaning
|
< 1
|
Varies
|
Industrial laundry pre-spotter and detergent
|
2 to 4
|
Varies
|
Remover and stripper
Products containing d-limonene are used as removers and/or strippers for industrial purposes. The applications, concentration of d-limonene and package size are listed in Table 7.4.
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