viContents
3.2
Battery
Parameters30
3.2.1Cell and Battery Voltages30
3.2.2Charge (or Amphour) Capacity31
3.2.3Energy Stored32
3.2.4Specific Energy33
3.2.5Energy Density33
3.2.6Specific Power34
3.2.7Amphour (or Charge) Efficiency34
3.2.8Energy Efficiency35
3.2.9Self-discharge Rates35
3.2.10Battery Geometry35
3.2.11Battery Temperature, Heating and Cooling Needs35
3.2.12Battery Life and Number of Deep Cycles35
Lead Acid Batteries36
3.3.1Lead Acid Battery Basics36
3.3.2Special Characteristics of Lead Acid Batteries38
3.3.3Battery Life and Maintenance40
3.3.4Battery Charging40
3.3.5Summary of Lead Acid Batteries41 3.4
Nickel-Based Batteries
41
3.4.1Introduction41
3.4.2Nickel Cadmium41
3.4.3Nickel Metal Hydride Batteries44 3.5
Sodium-Based Batteries
46
3.5.1Introduction46
3.5.2Sodium Sulfur Batteries47
3.5.3Sodium Metal Chloride (ZEBRA) Batteries48 Lithium Batteries
50
3.6.1Introduction50
3.6.2The Lithium Polymer Battery50
3.6.3The Lithium Ion Battery51 3.7
Metal–Air Batteries
52
3.7.1Introduction52
3.7.2The Aluminium–Air Battery52
3.7.3The Zinc–Air Battery53 3.8
Supercapacitors and Flywheels
54
3.8.1Supercapacitors54
3.8.2Flywheels56 Battery Charging
59
3.9.1Battery Chargers59
3.9.2Charge Equalisation60 The Designer’s Choice of Battery
63
3.10.1Introduction63
3.10.2Batteries which are Currently Available Commercially63 Use of
Batteries in Hybrid Vehicles64
3.11.1Introduction64
Contents
vii3.11.2IC/Battery Electric Hybrids64
3.11.3Battery/Battery Electric Hybrids64
3.11.4Combinations using Flywheels65
3.11.5Complex Hybrids65 Battery Modelling
65
3.12.1The Purpose of Battery Modelling65
3.12.2Battery Equivalent Circuit66
3.12.3Modelling Battery Capacity68
3.12.4Simulating a Battery at a Set Power71
3.12.5Calculating the Peukert Coefficient75
3.12.6Approximate Battery Sizing76 In Conclusion
77
References
78
4Electricity Supply794.1
Normal Existing Domestic and Industrial Electricity Supply Infrastructure Needed for Charging Electric Vehicles Electricity Supply Rails Inductive Power Transfer for Moving Vehicles Battery Swapping
84
Further Reading
85
5Fuel Cells875.1
Fuel Cells – A Real Option Hydrogen Fuel Cells – Basic Principles
89
5.2.1Electrode Reactions89
5.2.2Different Electrolytes90
5.2.3Fuel Cell Electrodes93 Fuel Cell Thermodynamics – An Introduction
95
5.3.1Fuel Cell Efficiency and Efficiency Limits95
5.3.2Efficiency and the Fuel Cell Voltage98
5.3.3Practical Fuel Cell Voltages100
5.3.4The Effect of Pressure and Gas Concentration101 Connecting Cells in Series – The Bipolar Plate Water Management in the PEMFC
106
5.5.1Introduction to the Water Problem106
5.5.2The Electrolyte of a PEMFC107
5.5.3Keeping the PEM Hydrated109 Thermal Management of the PEMFC
110 A Complete Fuel Cell System Practical Efficiency of Fuel Cells
114
References
114
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