Guidance for the inventory of polybrominated diphenyl ethers (pbdes) listed under the Stockholm Convention on Persistent Organic Pollutants



Download 0.85 Mb.
Page2/21
Date01.02.2017
Size0.85 Mb.
#14871
1   2   3   4   5   6   7   8   9   ...   21



Table of Contents




1Introduction 9

1.1Purpose of the guidance document 9

1.2Objectives of the inventory 10

1.3Structure of the guidance 10



2Background information on c-PentaBDE, c-OctaBDE and HBB 12

2.1POP-PBDEs and HBB in the Convention 12

2.2Production of commercial PBDE mixtures and HBB 13

2.3Former uses of POP-PBDEs 14

2.3.1Former uses of c-PentaBDE 14

2.3.2Former uses of c-OctaBDE 16

2.4Former uses of HBB 17

2.5POP-PBDEs in material/recycling flows and at end-of-life 17

2.5.1C-PentaBDE in reuse, recycling and waste flows 17

8.1.1C-OctaBDEs in reuse, recycling and waste flows 20

10.1Potential contaminated sites 21

11How to conduct a POP-PBDEs inventory 22

11.1Step 1: Planning the inventory 24

11.1.1Establish a national inventory team 24

11.1.2Identify key stakeholders 24

11.1.3Define the scope of the inventory 27

11.1.4Develop the work plan 28

11.2Step 2: Choosing data collection methodologies 28

11.2.1Tiered approach 28

Tier I: Initial assessment 29

Tier II: Preliminary inventory 30

Tier III: In-depth inventory 30

11.2.2Indicative, qualitative and quantitative methodologies 30

15.1Step 3: Collecting and compiling data from key sectors 32

15.2Step 4: Managing and evaluating the data 33

15.2.1Data management 33

15.2.2Mechanism for evaluation of the inventory 33

15.3Step 5: Preparing the inventory report 34

16Inventory of POP-PBDEs in electrical and electronic equipment (EEE) and related waste (WEEE) 35

16.1Step 1: Planning the inventory and identifying stakeholders 36

16.2Step 2: Choosing data collection methodologies 36

16.2.1Tier I: Initial assessment 36

16.2.2Tier II: Preliminary inventory of POP-PBDEs in CRT casings 38

16.2.3Tier III: In-depth inventory of POP-PBDEs-containing EEE/WEEE 38

16.3Step 3: Collecting and compiling data from sectors 39

16.3.1Inventory of stocks and flows of EEE/WEEE 40

1.1.1.1Imports of new and second-hand EEE 40

1.1.1.2EEE in use or stored at the consumer level (stocks) 43

1.1.1.3EEE entering the waste stream 46

16.3.2Total polymer fraction in relevant EEE/WEEE 47

16.3.3POP-PBDEs content in the polymer fraction 47

16.3.4How to use collected data for the estimation of the POP-PBDEs inventory 48

1.1.1.4POP-PBDEs in imported EEE 49

1.1.1.5POP-PBDEs in stocks of EEE 49

1.1.1.6POP-PBDEs in EEE entering the waste stream 50

1.1.1.7POP-PBDEs in secondary polymers from recycling from WEEE and imports 51

16.3.5Recalculation from c-OctaBDE content to POP-PBDEs 52

16.4Step 4: Managing and evaluating data 52

16.5Step 5: Preparing the inventory report 53

17Inventory of POP-PBDEs in the transport sector 53

17.1Step 1: Planning the inventory 53

17.2Step 2: Choosing data collection methodologies 54

17.2.1 Tier I: Initial assessment 54

17.2.2Tier II: Preliminary inventory 55

17.2.3Tier III: In-depth inventory 56

17.3Step 3: Compiling data from sectors 56

17.3.1Amount of POP-PBDEs in impacted cars, trucks and buses 57

17.3.2Total use of POP-PBDEs in transport, regional use patterns and related impacted factors 58

17.3.3General formula to calculate POP-PBDEs in vehicles 59

17.3.4Individual stages of the vehicle life cycle for data compilation 59

17.3.5Calculation of POP-PBDEs of vehicles in current use/sale 61

17.3.6Calculation of POP-PBDEs in imported/exported vehicles 62

17.3.7Calculation of POP-PBDEs in ELVs for the respective inventory year 63

17.3.8Calculation of POP-PBDEs in historically disposed wastes from vehicles 64

17.3.9Calculation of listed PBDEs in the transport sector 65

17.3.10Estimation of POP-PBDEs from ELVs entering recycling processes 66

17.4Step 4: Managing and evaluating data 67

17.5Step 5: Preparing the inventory report 67

18Inventory of POP-PBDEs in other uses 67

18.1Inventory approach for POP-PBDEs in other uses 68

18.1.1POP-PBDEs-containing furniture, mattresses and rebond material 69

18.1.2POP-PBDE-containing textiles 69

18.1.3POP-PBDE-containing construction materials 69

18.1.4POP-PBDEs in rubber 70

18.1.5Former POP-PBDEs use in drilling operation 70

19POP-PBDEs-contaminated sites 70

19.1Scope and background information 70

19.2Inventory approach for potential POP-PBDE-contaminated sites 71

19.2.1Step 1: Planning the inventory 71

19.2.2Steps 2 and 3: Methods for collecting and compiling data to identify potential POP-PBDEs sites 73

19.2.3Step 4: Managing/evaluating data 74

19.2.4Step 5: Reporting of potential POP-PBDE-contaminated sites. 79

References 80

Annexes 87

Annex 1. List of E-waste inventories from developing countries 87

Annex 2. Questionaire for EEE importers 88

Annex 3. Questionaire for households (EEE) 95

Annex 4. Questionaire for corporate and institutional consumers 101

Annex 5. Questionaire for WEEE recyclers 108

Annex 6. Federal Environmental Quality Guidelines for Polybrominated Diphenyl Ether 118



List of Figures


List of Tables


Abbreviations and acronyms


ABS acrylonitrile-butadiene-styrene

ASR automotive shredder residue

BAT/BEP best available technologies/best environmental practices

BFR brominated flame retardant

c-PentaBDE commercial pentabromodiphenylether (TetraBDE and PentaBDE)

c-OctaBDE commercial octabromodiphenyl ether (hexaBDE and heptaBDE)

COP Conference of Parties

CRT cathode ray tube

DecaBDE decabromodiphenyl ether

DSI detailed site investigation

EEE electrical and electronic equipment

ELV end-of-life vehicle

EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt

EPS expanded polystyrene

ESM environmentally sound management

EU European Union

FEQGs Federal Environmental Quality Guidelines (Canada)

GC/MS gas chromatography/mass spectrometry

HBB hexabromobiphenyl

HBCD hexabromocyclododecane

HIPS high impact polystyrene

HS Harmonized Commodity Description and Coding Systems

LCD liquid crystal display

MCV maximum concentration value

NGOs non-governmental organization

NIP national implementation plan

IT information technology

PBB polybromobiphenyl

PBDE polybrominated diphenyl ether

PBT polybutylene terephthalate

PC personal computer

POPs persistent organic pollutants

POP-BDEs persistent organic pollutants-polybrominated diphenyl ethers

PSI preliminary site investigation

PUR polyurethane

PVC polyvinyl chloride

RoHS Restriction of the use of certain hazardous substances in electrical and electronic equipment

SAICM Strategic Approach to International Chemical Management

SC Stockholm Convention

SCCP short-chain chlorinated paraffins

TV television

UK United Kingdom

US United States

WEEE waste electrical and electronic equipment

XRF X-ray fluorescence

XPS extruded polystyrene





Download 0.85 Mb.

Share with your friends:
1   2   3   4   5   6   7   8   9   ...   21




The database is protected by copyright ©ininet.org 2024
send message

    Main page