The SDWA is the final federal law governing flowback water management. It establishes the Underground Injection Control (UIC) program, which regulates waste injections into six categories of wells. The UIC regulations are designed to ensure that injected gases and wastewater do not migrate upward and pollute groundwater. Class II wells are the most relevant to underground storage of flowback water (Figure 5.1). Other sections of the law, such as those that regulate water injected into the wellbore during the fracturing process, are discussed in Chapter 4.
Underground injection is a standard process for dealing with flowback water in other regions where shale gas occurs (such as the Barnett shale of Texas). However, injection well capacity in the Marcellus shale region is extremely limited. In Pennsylvania, for example, eight permitted disposal wells may each accept an average of 42,000 gallons per day.254 Due to limited capacity, underground injection is not expected to be a viable option for managing flowback water in the Marcellus play. There is little additional opportunity to dispose of flowback water other than to transport it to states outside of the Marcellus play.
State laws
In addition to the ECPRA, CWA, and SDWA, individual states may have their own water quality laws. Gas companies must comply with state and local laws and regulations when drilling.
Maryland prohibits any wastes that would be toxic to residents or impair navigation to be discharged into receiving waters.1 In addition, Maryland expressly forbids any underground injection of wastes.255 The state’s expectations are that gas companies will transport their flowback water out of the state for disposal rather than find in-state solutions.256
New York prohibits discharge of radioactive waste into receiving waters through its Environmental Conservation Law 2 Flowback water with high radium-226 levels could be regulated under the law.
Pennsylvania requires additional treatment for residual wastes under its Solid Waste Management Act. Drill cuttings from oil and gas mining are omitted, as long as they are disposed of properly at the rig.257
West Virginia does not have additional wastewater treatment or management laws beyond the CWA. However, West Virginia Department of Environmental Protection’s “Oil and Gas Industry Guidance” suggests that gas companies consider recycling flowback water as a means of dealing with waste.258
Flowback water treatment options
Due to CWA rules affecting pretreatment and direct discharge into receiving waters, SDWA requirements and limited underground injection capacity in Marcellus shale states, and the varied state laws, wastewater treatment plants and gas companies must invest in treatment technologies. Many treatment facilities are exploring these technologies, as demonstrated by expanded recycling and reuse and less reliance on conventional treatment (Figure 5.2).
Figure 5.2: Flowback Water Treatment options are expanding.
Source: Swistock, Bryan. 2010. “Water Issues Related to Marcellus Gas Drilling Activity. Available online at http://www.empoweredmunicipality.com/library/files/PSATSApril2010-Marcellus.2.pdf
A main option for gas companies is to recycle or reuse flowback water. Any remaining water should be pretreated or treated by wastewater treatment plants for TDS and additional chemical discharge restrictions (if such restrictions exist considering lack of available chemical components from MSDS). Various technologies exist to fill the needs of gas companies and wastewater treatment plants.
Recycling
Gas companies that recycle flowback water may need to treat it to a minimum level of quality. Figure 5.3 shows the difference between conventional limits for water treatment and characteristics of flowback water.
Figure 5.3: Recycled flowback water may need treatment.
Parameter
|
Conventional limits
|
Blended Marcellus water
|
pH
|
6.0 to 8.0
|
1,500 mg/L
|
Chlorides
|
<25 mg/L
|
1 million/100 mL
|
Iron
|
<50 mg/L
|
Ca – 4,200 mg/L,
Mg – 488 mg/L,
|
Ca, Mg, Ba, SO4
|
<100/100 mL
|
Ba – 39 mg/L,
SO4 – 124 mg/L
|
Bacteria count
|
ƒ(P,T,pH) (+/- 350 mg/L)
|
14.5 mg/L
|
Suspended solids
|
<20 mg/L
|
26,000 mg/L
|
Oil and soluble organics
|
<20,000 mg/L
|
4.6 mg/L
|
Source: Guadlip, Tony, et al. 2008. Marcellus Shale Water Management Challenges in Pennsylvania. Paper for presentation at the 2008 Society of Petroleum Engineers Shale Gas Production Conference, Fort Worth, Texas, U.S.A., 16-18 November 2008.
Most recycling efforts focus on removing total dissolved solids (TDS), including chlorides and calcium. Selected technologies to remove TDS include:259
Reverse osmosis: The reverse osmosis process forces wastewater through a selective membrane, yielding high concentration and low concentration solutions. The low concentration solution may require finishing through pH stabilization or mineralization. The high concentration solution is a waste product and must be disposed. Nanofiltration: Nanofiltration is similar to reverse osmosis, but requires less energy. Approximately 75 to 90 percent of the feed water is recovered, so minor amounts of high concentration brine is produced. Electrodialysis: The electrodialysis process treats water as it flows between a stack of anion- and cation-exchange membranes. The membranes work together to systematically concentrate pollutants. System costs are high but recovery rates are significant, with nearly 90 percent of feed water consistently reclaimed.
Freeze thaw
The freeze thaw process begins when freezing water below 32F is sprayed into an ice pile. Runoff contains high TDS concentrations when the ambient temperature is freezing or below. Conversely, runoff contains low TDS concentrations when the ambient temperature is above freezing. The limiting factors to using freeze thaw technology are the climate of the region where it is used and the large area it requires. A 1,000 barrel per day facility would require tens of acres for treatment. An additional recycling option still in development would use acid mine drainage (AMD) as a source of water for hydrofracking. AMD is abundant in former coal-producing regions such as the northeast United States because it forms when coal mining exposes rainwater and groundwater to pyrite and other chemicals. The resulting fluid is high in sulfuric acid, iron hydroxide, sulfates, and suspended solids. If left untreated, runoff into water bodies causes metal oxides to form an impervious surface on the bed of receiving water. The impervious surface destroys the aquatic ecosystem.
Researchers at Carnegie Mellon University recently received a $1 million grant from the U.S. Department of Energy to explore using acid mine drainage to remove electrochemical cells to achieve minimum water quality requirements necessary to use for hydraulic fracturing.260 In addition, at least one water reclamation company, STW Resources, has adapted the large-scale acid mine drainage treatment process for use at drilling operations. Large treatment plants normally oxidize the acid mine drainage in lagoons and alter the pH level by adding lime and other base chemicals. The STW process completes the same process in a mobile unit. The unit can handle 360,000 gallons per day and costs are mitigated substantially by government grants and subsidies.261
Reuse
Water that meets minimum criteria may be simply reused. Range Resources announced in October 2009 that it would reuse 100 percent of the flowback water from its operations in Washington County, Pennsylvania.262 Reusing does not produce any concentrated brine that must be disposed. However, it is important to note that, while 100 percent of reclaimed water will be recycled, only nine to 35 percent of water injected into a wellbore comes back to the surface.263
Evaporation In western states drillers often leave flowback water in a lined pit and allow it to evaporate naturally (Figure 5.5). The resulting solid residue is composed mostly of TDS and can be sold to local governments for cold weather road treatment or disposed of as a solid under applicable laws.
Figure 5.5: Evaporation pits are used to manage flowback water in Western states.
Source: Gaudlip, Tony. “Preliminary Assessment of Marcellus Water Reuse.” 2010
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