Structure, Bonding and properties Why do atoms bond together?


The Properties of simple covalent molecular substances -



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chemical bonding
0539 s18 qp 01
The Properties of simple covalent molecular substances -
small molecules!

The electrical forces of attraction, that is the chemical bond
*
, between atoms in any molecule are
strong and most molecules do not change chemically on moderate heating.(
* sometimes referred to as the
intramolecular bond
)

However
, the electrical forces
**
between molecules are weak and easily weakened further on
heating.

These weak attractions are known as
**
intermolecular forces and consequently the bulk material is not
usually very strong.

Consequently small covalent molecules tend to be volatile liquids, easily vapourised, or low melting
point solids.

On heating the inter-molecular forces are easily overcome with the increased kinetic energy gain of the particles and so have low melting and boiling points.

They are also poor conductors of electricity because there are no free electrons or ions in any state to carry electric charge.

Most small molecules will dissolve in a solvent to form a solution.
Large Covalent Molecules and their Properties



7
(macromolecules - giant covalent networks and polymers) It is possible for many atoms to linkup to form ab giant covalent

structure or lattice. The atoms are usually non-metals.

This produces ab very strong dimensional covalent bond network orb blatticeb.bThis gives them significantly different properties from the small

simple covalent molecules mentioned above.

This is
illustrated by carbon in the form of diamond
. Carbon can form four single bonds so each carbon bonds to four others etc.

This type of structure is thermally very stable and they have high melting

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