Batteries, Flywheels and Supercapacitors
31External load
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Figure 3.1Simple equivalent circuit model of a battery. This battery is composed of six cells the state of charge and other factors such as temperature. This is dealt within more detail in Section 3.12, where we address the problem of modelling the performance of batteries.
3.2.2 Charge (or Amphour) CapacityThe electric charge that a battery can supply is clearly a most crucial parameter. The SI
unit for this is the coulomb – the charge when 1 A flows for 1 second. However, this unit is inconveniently small. Instead the amphour is used – 1 A flowing for 1 hour. The capacity of a battery might be, say, ‘10 Ah. This means that it can provide 1 A for hours, or 2 A for 5 hours, or, in theory, 10 A for 1 hour. However, in practice, it does notwork out like this for most batteries.
It is usually the case that while a battery maybe able to provide 1 A for 10 hours,
if A is drawn from it, it will last less than 10 hours. It is most important to understand this. The capacity of the large batteries used in EVs (traction batteries) is usually quoted fora hour discharge. Figure 3.2 shows how the capacity is affected if the charged is removed more quickly, or more slowly. The diagram is fora nominally 100 Ah battery.
Notice that if the charge is removed in 1 hour, the capacity falls very considerably to about 70 Ah. On the other hand, if the current is drawn off more slowly, in say 20 hours,
the capacity rises to about 110 Ah.
This change is capacity occurs because of unwanted side reactions inside the cell. The effect is most noticeable in the lead acid battery, but occurs in all types. It is very important to be able to predict accurately
the effects of this phenomenon, and this is addressed in
Section 3.12, when we consider battery modelling.
The charge capacity leads to an important notational point that should be explained here. The capacity of a battery in amphours is represented by the letter
C . However,
somewhat confusingly, till you get used to it, this is also used to represent a current.
Suppose a battery has a capacity of 42 Ah then it is said that
C = 42 A. Battery users talk about a discharge current of 2
C ’, or charging the battery at 0.4
C ’. In these cases this would mean a discharge current of 84 A, or a charging current of 16.8 AA further refinement is to use a subscript with the
C symbol.
As we noted above,
the amphour capacity of a battery varies with the time taken for the discharge. In our example, the 42 Ah battery is rated thus fora hour discharge. In this more complete notation, a discharge current of 84 A should be written as 2
C10
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2 4
6 Discharge time / hours
Graph showing change in battery capacity with discharge time
Capacity / Amphours
12 14 16 18 20
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