3Batteries, Flywheels and Supercapacitors
3.1IntroductionWe have seen in the previous chapter that there are many different types and sizes of
EVs. However, in nearly all road vehicles the battery is a key component. In the classical EV the battery
is the only energy store, and the component with the highest cost,
weight and volume. In hybrid vehicles the battery, which must continually accept and give out electrical energy, is also a key component of the highest importance. Some fuel cell (FC) vehicles have been made which have batteries that are no larger than those normally fitted to IC engine cars, but it is probably that most early FC-powered vehicles will have quite large batteries and work in hybrid FC/battery mode. In short, a good understanding of battery technology and performance is vital to anyone involved with electric road vehicles.
What is an electric battery A battery consists of two or more electric cells connected together. The cells convert chemical energy to electrical energy. The cells consist of positive and negative electrodes in an electrolyte. It is the chemical reaction between the electrodes and the electrolyte which generates DC electricity. In the case of secondary or rechargeable batteries the chemical reaction can be reversed by reversing the current and the battery returned to a charged state.
The lead acid battery is the
traditional rechargeable type, but there are others which are becoming popular in modern EVs. The first EV using rechargeable batteries preceded the invention of the rechargeable lead acid battery by a quarter of a century,
and there area very large number of materials and electrolytes that can be combined to form a battery. However, only a relatively small number of combinations have been developed as commercial rechargeable electric batteries suitable for use in vehicles. At present these include lead acid, nickel iron, nickel cadmium, nickel metal hydride (NiMH),
lithium polymer and lithium iron, sodium sulfur and sodium metal chloride. There are also more recent developments of batteries that can be mechanically refuelled, the main ones being aluminium–air and zinc–air. Despite all the
different possibilities tried, and
Electric Vehicle Technology Explained, Second Edition. James Larminie and John Lowry.
© 2012 John Wiley & Sons, Ltd. Published 2012 by John Wiley & Sons, Ltd.
30Electric Vehicle Technology Explained, Second Edition about 150 years of development, a suitable battery has only recently been developed which allows mass production of EVs.
From the EV designer’s point of view the battery can be treated as a black box that has a range of performance criteria. These criteria will include specific energy, energy density, specific power, typical voltages, amphour efficiency, energy efficiency,
commercial availability, cost, operating temperatures, self-discharge rates, number of life cycles and recharge rates – terms which will be explained in the following section. The designer also needs to understand how energy availability varies with ambient temperature, charge and discharge rates, battery geometry,
optimum temperature, charging methods, cooling needs and likely future developments. However, at least a basic understanding of the battery chemistry is very important, otherwise the performance and maintenance requirements of the different types, and most of the disappointments connected with battery use,
such as their limited life,
self-discharge, reduced efficiency at higher currents, and so on,
cannot be understood. This basic knowledge is also needed in regard to likely hazards in an accident and the overall impact of the use of battery chemicals on the environment.
Recycling of used batteries is also becoming increasingly important.
The main parameters that specify the behaviour and performance of a battery are given in the following section. In the later sections the chemistry and performance of the most important battery types are outlined, and finally the very important topic of battery performance modelling is outlined.
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