Electric vehicle



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Electric Vehicle Technology Explained, Second Edition ( PDFDrive )
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Cl

+

2Na
2Na
+
+ 2Cl

+ 2e

2NaCl
NiCl
2
Ni
2
+
+ 2Cl

+ 2e

Ni
Figure 3.10
The reactions at each electrode of the sodium metal chloride battery during discharge
Table 3.5
Nominal battery parameters for sodium metal chloride (Zebra) batteries
Specific energy Wh kg
−1
Energy density Wh l
−1
Specific power W kg
−1
Nominal cell voltage V average (2.5 V when fully charged)
Amphour efficiency
Very high
Internal resistance
Very low, but higher at low levels of charge
Commercially available
Available commercially, but very few suppliers
Operating temperature
300–350

C
Self-discharge
When not in use energy must be continually used to keep the battery up to temperature, corresponding to a self-discharge of about 10% per day
Number of life cycles
>1000
Recharge time h
Figure 3.11
A commercial Zebra battery fitted neatly under the seat of an experimental battery electric vehicle by MES-DEA. The battery stores about 18 kWh of electrical energy


50
Electric Vehicle Technology Explained, Second Edition of energy. However, when not in use it consumes about 100 W of power keeping up to temperature. So, in a 24 hour period the heating will require 0
.1 × 24 = 2.4 kWh of energy, corresponding to about 13% of the stored energy. In energy terms, this corresponds to the self-discharge of other types of battery, and is quite a high figure.
Zebra batteries can be allowed to cool, but if this happens they must be reheated slowly and steadily, a process typically taking about 24 hours. They are available as tried and tested units with well-established performance criteria, though only in a very limited range of size. An example is shown in Figure The overall characteristics of the battery are given in Table 3.5. These are taken from the kWh (
∼280 V, 64 Ah, 180 kg, 32 kW peak power) unit manufactured by MES-DEA
of Switzerland.

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