SAFETY DATA SHEET1 Identification of the substance or preparation and of the company/undertaking Product Name: Datasheet Number: 777014 1. 0. 0 Use of the substance/preparation: Oil Spill Dispersant Product Part Number: 777014 (25L) Head Office:: Wilhelmsen Ships Service AS address: Strandveien 20, N1324 Lysaker .: Norway, Tel(+47) 67 58 45 50 Name of Supplier: Wilhelmsen Ships Service AS Address of Supplier: Willem Barentszstraat 50 3165AB Rotterdam The Netherlands Telephone: +31 10 4877 777 Fax: +31 10 4877 888 Responsible Person: Patrick Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35 Email: Patrick.Rijsdijk@Wilhelmsen.com Emergency Telephone: **ONLY TO BE USED IN CASE OF AN INCIDENT** NCEC: +44 1865 407333, CHEMTREC (800) 424 9300 American Chemistry Council +1 703 527 3887, Greece +30 210 7793777 2 Hazards identification Harmful - Odour: Smells of hydrocarbon - Appearance: Liquid, light, brown - Contact with eyes: Causes redness and irritation - Inhalation: Mildly irritating to respiratory systemClassification of the substance or mixture - Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations. - Harmful if swallowed. - May cause damage to the lungs - Repeated exposure may cause skin dryness or cracking. Risk Phrases - Harmful: may cause lung damage if swallowed (R65) - Repeated exposure may cause skin dryness or cracking (R66) Safety Phrases - Do not breathe spray/mists (S23) - Do not breathe vapour/fumes (S23) - Avoid contact with skin and eyes (S24/25) - Wear suitable protective clothing, eye/face protection and gloves (S36/37/39) - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label (S62) Date of Last Change 31/05/2011 1
NALFLEET MAXI-CLEAN 2 3 Composition/information on ingredients Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols Kerosine 60-90% 64742-47-8 265-149-8 R65, 66 Xn *See Section 16 4 First aid measures Contact with skin - IF ON SKIN: Wash with plenty of soap and water. - Remove contaminated clothing Contact with eyes - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. - If eye irritation persists: Get medical advice/attention. Ingestion - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. - Give water or milk to drink Inhalation - IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. - Remove victim to fresh air and keep at rest in a position comfortable for breathing. - IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. - May cause unconsciousness 5 Fire-fighting measures - Lower flammability limit 0,60%(in air), Upper flammability limit 5,5%(in air), Flash point 73 deg C (CC) - Decomposition products may include toxic and irritant fumes, Carbon dioxide may be formed, Carbon oxides may be formed - In case of fire use water spray or fog, alcohol resistant foam, dry chemical or carbon dioxide (S43) - Keep container(s) exposed to fire cool, by spraying with water - In the event of an adjacent fire, cool containers with water spray - Vapours are heavier than air and may travel considerable distances to a source of ignition and flashback 6 Accidental release measures Personal precautions, protective equipment and emergency procedures - Wear protective clothing as per section 8 Environmental Precautions - No special precautions are required for this product Methods and material for containment and cleaning up - Ventilate area- Absorb spillage in earth or sand - Collect spillage. - Remove contaminated material to safe location for subsequent disposal - Wash to waste with plenty of water 7 Handling and storage Date of Last Change 31/05/2011 2
NALFLEET MAXI-CLEAN 2 7 Handling and storage (....) Precautions for safe handling - Eyewash bottles should be available - Avoid contact with skin and eyes (S24/25) Conditions for safe storage, including any incompatibilities - Keep in a cool, dry, well ventilated place - Keep container tightly closed. 8 Exposure controls/personal protectionControl parameters - Kerosine TLV (TWA) 275 mg/m3 ( ) Exposure controls - No special precautions are required for this product Occupational exposure controls - Respiratory protection may be required under exceptional circumstances when excessive air contamination exists - Wear suitable protective clothing, including eye/face protection and gloves (rubber are recommended) 9 Physical and chemical properties - Odour: Smells of hydrocarbon - Appearance: Liquid, light, brown - Boiling point 195 °C to 245 °C at 760 mm /Hg - Density 0,80 g/cm3 at 20 deg C - Lower flammability limit 0,60%(in air), Upper flammability limit 5,5%(in air), Flash point 73 deg C (CC) 10 Stability and reactivity - This article is considered stable under normal conditions11 Toxicological information Information on toxicological effects - No information available Inhalation - In cases of severe exposure, dizziness, confusion, headache or stupor may develop Contact with skin - Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis Contact with eyes - Causes redness and irritation Ingestion - The ingestion of significant quantities may cause chronic pneumonitis - Causes damage to the lungs 12 Ecological information Ecotoxicity - LC50 (fish) (Kerosene) >100 mg/l (96 hr) - EC50 (daphnia) (Kerosene) >100 mg/l (48 hr) - Biodegradability. OECD-test. 28 days >60 % (Kerosene) Date of Last Change 31/05/2011 3
NALFLEET MAXI-CLEAN 2 12 Ecological information (....) Persistence and degradability - No information available Bioaccumulation Potential - Hydrocarbon solvents have the potential to bioaccumilate. Mobility in soil - Large volumes may penetrate soil and contaminate groundwater - Substance remaining on soil surface evaporated within one day- Dispersible 13 Disposal considerations Waste treatment methods - Disposal should be in accordance with local, state or national legislation - Dispose of contents/container to an authorised waste collection point Classification - EU Waste class: 07 01 14 Transport information Special precautions for user - Not classified as hazardous for transport 15 Regulatory information Classification and labelling- A REACH chemical safety assessment has not been carried out - Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations. Safety, health and environmental regulations/legislation specific for the substance or mixture - This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and Directive 453/2010/EU. - This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive (67/548/EEC) 16 Other information Text of R and S phrase codes used in this safety data sheet:- R65: Harmful: may cause lung damage if swallowed; R66: Repeated exposure may cause skin dryness or cracking. The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in terms of safety requirements and does not signify any warranty with regard to the product's properties The data given here only applies when product used for proper application(s). The product is not sold as suitable for other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s) without seeking advice from manufacturer The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the individual constituents Date of Last Change 31/05/2011 4
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