Appendix 2-5: Rejected ecotox bibliography Excluded



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monitored in the tissues of some birds of prey (wild birds), some species of algae, fish and crustaceans. The results obtained revealed: (1) The presence of some Organochlorines (OC) in the tissues of many of the tested birds represented in (DDE, Heptachlore, HCH, Dicofole). (2) The presence of high residues of Organophosphorus (OP) pesticides represented in malathion and diazinon in most of the tested birds. But they were not detected with high levels in any of fish, crustaceans or algae. (3) The presence of high concentrations of (OC) compounds in the tissues of algae, crab, mullet and some birds (moorhen-cormorant and gulls). Meanwhile, none of those compounds was detected in the water samples. (4) The presence of high levels of all detected pesticides in the tissues of crab makes it the very acceptable bioindicator to mirror the pollution of the lake, then followed by algae. (5) Pollutants can be transferred through the food chain which causes biomagnification of them in the bodies of the higher organisms in the food chain. It could be concluded that implementation of the environmental management practices in Lake Temsah is still needed to protect these ecosystems from more pollutions which could affect human health and environment.
Keywords: Aquatic organisms
Keywords: D 04070:Pollution
Keywords: Food chains
Keywords: Organochlorine compounds
Keywords: Ecosystems
Keywords: Water sampling
Keywords: Environmental health
Keywords: Freshwater
Keywords: Microbiology Abstracts C: Algology, Mycology & Protozoology; Pollution Abstracts; ASFA 3: Aquatic Pollution & Environmental Quality; Ecology Abstracts
Keywords: Toxicity tests
Keywords: Malathion
Keywords: Public health
Keywords: Lakes
Keywords: Insecticides
Keywords: Pollutants
Keywords: Egypt, Arab Rep., Suez Canal
Keywords: Pollution
Keywords: Algae
Keywords: Freshwater pollution
Keywords: Bioindicators
Keywords: Pollution detection
Keywords: Decapoda
Keywords: P 2000:FRESHWATER POLLUTION
Keywords: Crustacea
Keywords: DDE
Keywords: K 03450:Ecology
Keywords: Q5 01504:Effects on organisms
Keywords: Birds of prey
Keywords: Water pollution
Keywords: Aves
Keywords: Canals
Keywords: Pesticides
Keywords: hexachlorocyclohexane
Keywords: Fish
Keywords: Diazinon
Keywords: Environment management
Keywords: Indicator species English. Date revised - 2009-06-01. Last updated - 2012-03-29. DOI - MD-0009639981; 9313528; CS0935607; 1816-4927. SubjectsTermNotLitGenreText - Food chains; Pollution detection; DDE; Pesticides; Toxicity tests; Water pollution; Indicator species; Public health; Freshwater pollution; Aquatic organisms; Organochlorine compounds; Birds of prey; Malathion; Canals; Lakes; Pollutants; Diazinon; Pollution; Algae; Bioindicators; Ecosystems; Water sampling; Crustacea; Environmental health; Aves; Insecticides; hexachlorocyclohexane; Fish; Environment management; Decapoda; Egypt, Arab Rep., Suez Canal; Freshwater

204. Elwakeel, K. Z. and Yousif, A. M. Adsorption of malathion on thermally treated egg shell material. 2010; 61, 1035-1041.


Rec #: 13010
Keywords: CHEM METHODS
Notes: Chemical of Concern: MLN
Abstract: Abstract: Thermally treated egg shell materials were prepared at different temperatures. The samples were investigated by means of FT-IR and thermogravimetric analysis (TGA) The adsorption. behaviour of malathion on egg shell and its thermally treated samples was studied using batch method and gave uptake capacities up to 0.964 mmol/g. Adsorption kinetics as well as the adsorption isotherms were discussed. Regeneration of the loaded adsorbent beads towards the successive cycles was also clarified The adsorption of malathion is maintained untill the third. cycle without a significant activity loss.
Number of Volumes: 4
ISI Document Delivery No.: 563XI ://CCC:000275170400025

205. Elwan, Farid. Effective extraction and detection of some organophosphorus insecticides seized in Egypt: Abstracts of the 46th Congress of the European Societies of Toxicology. 2009 Sep 13-; 189, Supplement, (0): S219.


Rec #: 1700
Keywords: CHEM METHODS
Notes: Chemical of Concern: MLN
Abstract: Detection/ Desulphoration/ Degradation/ Organophosphorus insecticides http://www.sciencedirect.com/science/article/pii/S0378427409009692

206. Enayati, A. and Hemingway, J. Malaria Management: Past, Present, and Future. 2010; 55, 569-591.


Rec #: 13020
Keywords: REVIEW
Notes: Chemical of Concern: MLN
Abstract: Abstract: The prospect of malaria eradication has been raised recently by the Bill and Melinda Gates Foundation with support from the international community. There are significant lessons to be learned from the major successes and failures of the eradication campaign of the 1960s, but cessation of transmission in the malaria heartlands of Africa will depend on a vaccine and better drugs and insecticides. Insect control is an essential part of reducing transmission. To date, two operational scale interventions, indoor residual spraying and deployment of long-lasting insecticide-treated nets (LLINs), are effective at reducing transmission. Our ability to monitor and evaluate these interventions needs to be improved so that scarce resources can be sensibly deployed, and new interventions that reduce transmission in a cost-effective and efficient manner need to be developed. New interventions could include using transgenic mosquitoes, larviciding in urban areas, or utilizing cost-effective consumer products. Alongside this innovative development agenda, the potential negative impact of insecticide resistance, particularly on LLINs, for which only pyrethroids are available, needs to be monitored.
ISI Document Delivery No.: 545DG ://CCC:000273712100029

207. Ensminger, Michael P; Budd, Robert; Kelley, Kevin C, and Goh, Kean S. Pesticide Occurrence and Aquatic Benchmark Exceedances in Urban Surface Waters and Sediments in Three Urban Areas of California, Usa, 2008ă˘[Euro]"2011. 2013 May; 185, (5): 3697-710.


Rec #: 5360
Keywords: FATE
Notes: Chemical of Concern: MLN
Abstract: Abstract: Urban pesticide use has a direct impact on surface water quality. To determine the extent of pesticide contamination, the California Department of Pesticide Regulation initiated a multi-area urban monitoring program in 2008. Water and sediment samples were collected at sites unaffected by agricultural inputs in three areas: Sacramento (SAC), San Francisco Bay (SFB), and Orange County (OC). Samples were analyzed for up to 64 pesticides or degradates. Multiple detections were common; 50Ă‚ % of the water samples contained five or more pesticides. Statewide, the most frequently detected insecticides in water were bifenthrin, imidacloprid, fipronil, fipronil sulfone, fipronil desulfinyl, carbaryl, and malathion. Bifenthrin was the most common contaminant in sediment samples. Key differences by area: OC had more pesticides detected than SAC or SFB with higher concentrations of fipronil, whereas SAC had higher concentrations of bifenthrin. The most frequently detected herbicides were 2,4-D, triclopyr, dicamba, diuron, and pendimethalin. Key differences by area: OC and SFB had higher concentrations of triclopyr, whereas SAC had higher concentrations of 2,4-D and dicamba. Detection frequency, number of pesticides per sample, and pesticide concentration increased during rainstorm events. In water samples, all of the bifenthrin, malathion, fipronil, permethrin, and [lambda]-cyhalothrin detections, and most of the fipronil sulfone and cyfluthrin detections were above their lowest US EPA aquatic benchmark. Diuron was the only herbicide that was detected above its lowest benchmark. Based on the number of pesticides and exceedances of aquatic benchmarks or the high number of sediment toxicity units, pesticides are abundant in California surface waters.[PUBLICATION ABSTRACT]
Keywords: Environmental Monitoring
Keywords: Pesticides -- analysis
Keywords: California
Keywords: Geologic Sediments -- chemistry
Keywords: Water Pollutants, Chemical -- analysis
Keywords: Pesticides
Keywords: Water Pollution, Chemical -- statistics & numerical data
Keywords: Water Pollutants, Chemical
Keywords: Rivers -- chemistry
Keywords: Cities -- statistics & numerical data
Keywords: Environmental Studies English. Copyright - Springer Science+Business Media Dordrecht 2013. Last updated - 2013-06-03. DOI - 2983582321; 76822742; 108264; EVMT; 22899460; SPVLEVMT1066118552821

208. Entry, James a; Sojka, Robert E, and Entry, James A. Matrix-Based Fertilizers Reduce Pesticide Leaching in Soil. 2012 Mar; 223, (3 ): 1295-1302.


Rec #: 2790
Keywords: FATE
Notes: Chemical of Concern: MLN
Abstract: Abstract: The presence of pesticides in groundwater has been documented in several large-scale studies and numerous small-scale investigations. Pesticide leaching through soil has been identified as a major cause for the occurrence of these chemicals in surface and groundwater. We developed matrix-based fertilizers (MBFs) that have been shown to reduce N and P leaching. We tested the efficacy of the ionic bonds in the MBFs to reduce 2,4-dichlorophenoxyacetic acid (2,4-D), metolachlor, thiophanate methyl, carbaryl, diazinon, and malathion leaching in soil columns. After 7 days 2,4-D, thiophanate methyl, carbaryl, and malathion did not leach in sufficient quantities to determine if the MBF fertilizers reduced leaching compared with the control and the slow-release fertilizer Polyon registered . The MBF fertilizers leached from five to 30 times less metolachlor than the control and Polyon registered treatment. Treatments with MBF fertilizers leached from two to 72 times less diazinon than the control treatment. The MBF fertilizer treatment leached from eight to 268 less diazinon than columns receiving Polyon registered . The MBF formulations allow compounds with both anionic and cationic charges to bind with the Al(SO sub(4)) sub(3) 3H sub(2)O and/or Fe sub(2)(SO sub(4)) sub(3) 3H sub(2)O-lignin-cellulose matrix. When pesticides are added to the soil amended with matrix-based fertilizers, the ion exchange matrix will likely bind the metolachlor and diazinon to the Al(SO sub(4)) sub(3) 3H sub(2)O and/or Fe sub(2)(SO sub(4)) sub(3) 3H sub(2)O-starch-cellulose-lignin matrix thereby substantially reducing leaching. The MBFs could be used to limit both nutrients and pesticide leaching from agricultural fields.
Keywords: AQ 00001:Water Resources and Supplies
Keywords: SW 3050:Ultimate disposal of wastes
Keywords: Leaching
Keywords: P 2000:FRESHWATER POLLUTION
Keywords: Groundwater Pollution
Keywords: Agrochemicals
Keywords: Malathion
Keywords: Soil
Keywords: Fertilizers
Keywords: Agricultural Chemicals
Keywords: Ion Exchange
Keywords: Pesticides
Keywords: Environment Abstracts; Pollution Abstracts; Aqualine Abstracts; Water Resources Abstracts
Keywords: 2,4-Dichlorophenoxyacetic acid
Keywords: Groundwater
Keywords: Diazinon
Keywords: ENA 01:Air Pollution English. Date revised - 2012-03-01. Last updated - 2012-09-10. DOI - ee737da2-bdbd-4a24-98dbmfgefd101; 16383353; 0049-6979; 1573-2932. SubjectsTermNotLitGenreText - Soil; Fertilizers; Leaching; Pesticides; 2,4-Dichlorophenoxyacetic acid; Groundwater; Diazinon; Agrochemicals; Malathion; Agricultural Chemicals; Ion Exchange; Groundwater Pollution

209. ErdoÄŸrul, Ãâ zlem. Pesticide residues in liquid pekmez (grape molasses). 2008; 144, 323-328.


Rec #: 10570
Keywords: CHEM METHODS
Notes: Chemical of Concern: MLN
Abstract: Abstract: In this study 32 pesticide residues and eight polybrominated diphenlyl ether (PBDE) congeners were measured in seven liquid samples from Kahramanmaraş, Turkey. A new method based on the best recovery was column extraction with n-hexane/acetone followed by gas chromatography electron-capture detection (GC-ECD), and mass spectrometry (GC-MS). Limit of Detection (LOD) was 0.02 ng/g for PCBs and PBDEs and 0.05 ng/g for the others. α-HCH, γ-HCH, HCB, and Heptachlor were being measured in all LP samples. The sum of HCHs, DDTs and PCBs in samples was 1.56, 0.76 and 5.42 ng/g, respectively. p,p'-DDD, p,p'-DDT, o,p'-DDT, cis-nonachlor, β-endosulfan, endrin, PCB 118, PCB 138, PCB 180 and PBDEs were not detected. The mean values of α-HCH, β-HCH, γ-HCH, HCB were 0.72, 2.03, 1.92, 3.58 and α-chlordan, trans-nonachlor, heptachlor, malathion, aldrin, bromophos methyl, bromophos ethyl, cis-HCE, trans-HCE, chlordan, α-endosulfan, dieldrin were 2.44, 0.27, 1.25, 1.27, 0.91, 0.10, 0.50, 0.26, 0.63, 2.44, 0.30, 0.30 ng/g respectively. The mean values of p,p'-DDE, o,p'-DDE, o,p'-DDD were 0.26, 0.48, 0.68 and PCB 28, PCB 52, PCB 101, PCB 153 were 2.35, 35.27, 0.16, 0.18 ng/g, respectively.
Keywords: Liquid pekmez
Number of Volumes: 1-3
Dordrecht : Springer Netherlands http://dx.doi.org/10.1007/s10661-007-9995-5

210. ErgăĽN, Selma Să Nmez; OztăĽRk, Kahraman; Su, Ozlem; GăĽRsoy, Esra Baĺ˙Ar; Uä˙Urad, Iĺ˙Il, and YăĽKsel, Gă Kĺ˙En. Delayed Neuropathy Due to Organophosphate Insecticide Injection in an Attempt to Commit Suicide. 2009 Mar; 4, (1): 84-87.


Rec #: 7730
Keywords: HUMAN HEALTH
Notes: Chemical of Concern: MLN
Abstract: Abstract: Organophosphates (OPs) are commonly used as pesticides throughout the world. Exposures to OPs cause a significant number of poisonings and deaths every year. Organophosphate-induced delayed polyneuropathy is a sensory-motor distal axonopathy which usually occurs after exposure of certain OP insecticides. Neuropathies due to ingestion of OPs have rarely been reported in the literature. Moreover, until now, there is no report of a patient developing organophosphorus injection-induced delayed neuropathy in the literature. We report a patient with serious organophosphorus-induced delayed neuropathy due to malathion injection. The patient was a 32-year-old female who self-injected undetermined amounts of malathion over the median nerve trace on the forearm crease in a suicide attempt which resulted in peripheral neuropathy. eng. Date completed - 2010-06-28. Date created - 2009-03-13. Date revised - 2012-12-20. SuppNotes - Cites: Brain Res. 1989 Sep 4;496(1-2):228-40[2804632]; Cites: Biochem Pharmacol. 1984 Oct 15;33(20):3213-7[6487368]; Cites: Can J Neurol Sci. 1980 May;7(2):143-51[7407720]; Cites: Arq Neuropsiquiatr. 2002 Dec;60(4):1003-7[12563396]; Cites: Arh Hig Rada Toksikol. 2007 Sep;58(3):355-8[18050888]; Cites: Toxicol Lett. 2006 Mar 15;162(1):94-7[16309859]; Cites: Plast Reconstr Surg. 1982 Mar;69(3):482-90[7063571]; Cites: Orthop Clin North Am. 1981 Apr;12(2):239-44[7243237]; Cites: Skin Pharmacol Appl Skin Physiol. 2002 May-Jun;15(3):195-9[12077472]; Cites: Toxicol Rev. 2005;24(1):37-49[16042503]; Cites: Hand Clin. 1988 May;4(2):317-22[3294251]. Last updated - 2013-01-19. DOI - MEDL-18780003; 18780003; 1558-9447

211. Escuder-Gilabert, L.; Martin-Biosca, Y.; Sagrado, S.; Villanueva-Camanas, R. M., and Medina-Hernandez, M. J. Biopartitioning Micellar Chromatography to Predict Ecotoxicity. Departamento de Quimica Analitica, Universitat de Valencia, C/Vicente Andres Estelles s/n, E-46100 Burjassot, Valencia, Spain//: 2001; 448, (1/2): 173-185.


Rec #: 990
Keywords: MODELING,REFS CHECKED
Call Number: NO MODELING (24D,24DP,24DXY,ANT,BMY,BPH,CBD,CBL,CPY,DCF,DCNA,DMB,DMT,DPP1,DU,DZ,HFR,HTX,MDT,MLN,MLX,PAHs,PCP,PPG,TPR), NO REFS CHECKED (24D,24DP,24DXY,ANT,BMY,BPH,CBD,CBL,CPY,DCF,DCNA,DMB,DMT,DPP1,DU,DZ,HFR,HTX,MDT,MLN,MLX,PAHs,PCP,PPG,TPR)
Notes: Chemical of Concern: 24D,24DC,24DP,24DXY,2CP,4NP,ANT,BMY,BNZ,BPH,BPZ,CBD,CBL,CPY,Conazoles,DCF,DCNA,DMB,DMT,DPP1,DU,DZ,FMU,FNTH,HFR,HTX,ILL,MDT,MLN,MLX,PAHs,PCP,PIM,PL,PPG,TBA,TPR

212. Eto, M. Functions of Phosphorus Moiety in Agrochemical Molecules. 1997; 61, (1): 1-11.


Rec #: 1570
Keywords: CHEM METHODS
Call Number: NO CHEM METHODS (ACP,DDVP,DZ,FNT,FOSNH,FST,GFS,GYP,MLN,PFF,TCF)
Notes: Chemical of Concern: ACP,DDVP,DZ,FNF,FNT,FOSNH,FST,GFS,GYP,MLN,PFF,TCF

213. Fabacher, D. L. Hepatic Microsomes from Freshwater Fish - I. In Vitro Cytochrome P-450 Chemical Interactions. 1982; 73, 277-283.


Rec #: 540
Keywords: IN VITRO
Call Number: NO IN VITRO (24D,24DXY,AZ,CPY,ES,MLN,MP,PAQT,PCP,PPB,RTN,SZ,TVP)
Notes: Chemical of Concern: 24D,24DXY,AND,AZ,BAP,CHO,CPY,CdCl,DDT,DLD,EN,ES,HPT,MLN,MP,MRX,MXC,NS,NaCO,NaLS,OLEA,PAQT,PCL,PCP,PPB,RTN,SZ,TVP,TXP

214. Fabro, L. and Varca, L. M. Pesticide usage by farmers in Pagsanjan-Lumban catchment of Laguna de Bay, Philippines. 2012; 106, 27-34.


Rec #: 13060
Keywords: HUMAN HEALTH
Notes: Chemical of Concern: MLN
Abstract: Abstract: Pesticides have been of great benefit to agriculture in the Philippines by decreasing crop losses clue to insects, weeds, plant diseases, rodents, and other pests. However, they may build-up in the food chain and can cause contamination of the environment. We examined farmers' pesticide usage in southern sub-catchments of Laguna de Bay, which is a crucial water resource subject to intensive investigations to identify types and sources of pollution. Before the monitoring of pesticides in surface waters was commenced it was necessary to conduct a survey of the pesticides being used by the growers in the catchment in order to select the pesticides that should be monitored. Our survey found that nearly all growers in Lucban and Laguna, irrespective of crop grown, used the pyrethroid-based insecticides L-cyhalothrin and cypermethrin. In rice, pesticides were applied one to three times per season, while in vegetables, L-cyhalothrin and cypermethrin insecticides were applied five times and the other insecticides were applied two to four times throughout the cropping season. In Laguna other insecticides used were carbofuran, endosulfan and a formulated product of BPMC (fenobucarb) and chlorpyrifos. In Lucban other insecticides used were malathion, profenofos, chlorpyrifos, carharyl, niclosamide and metaldehyde. Butachlor and 2,4-D herbicides were used to control weeds and were applied once throughout the growing. Some fungicides were also applied. An estimation of the potential loads of chemicals moving into waterways has shown that L-cyhalothrin, pretilachlor, niclosamide, butalchlor, carbofuran and profenofos are most likely to be present in waterways in the Lucban and Pagsanjan regions in the largest quantities based on the quantities applied and/or use in a number of crops. (C) 2011 Published by Elsevier B.V.
ISI Document Delivery No.: 929PO ://CCC:000303078100005

215. Fadaei, Abdolmajid; Dehghani, Mohammad Hadi; Nasseri, Simin; Mahvi, Amir Hossein; Rastkari, Noushin, and Shayeghi, Mansoreh. Organophosphorous Pesticides in Surface Water of Iran. 2012 Jun; 88, ( 6): 867-9.


Rec #: 2630
Keywords: FATE
Notes: Chemical of Concern: MLN
Abstract: Abstract: This research aims to evaluate the presence and distribution of pesticides in Babolrood River of Mazandaran Province in Iran. Mean diazinon levels in surface water ranged from 77.6 to 101.6 ÎĽg L^sup -1^ with maximum level of 768.9 ÎĽg L^sup -1^ and mean malathion levels ranged from 55.7 to 75.9 ÎĽg L^sup -1^ with maximum level of 506.6 ÎĽg L^sup -1^. The residues of malathion and diazinon pesticides in all of the stations, 2 weeks after spraying, were more than allowed limits.[PUBLICATION ABSTRACT]
Keywords: Pesticides -- analysis
Keywords: Rivers
Keywords: Organophosphorus Compounds -- analysis
Keywords: Iran
Keywords: Water Pollutants, Chemical -- analysis
Keywords: Surface water
Keywords: Toxicity
Keywords: Diazinon -- analysis
Keywords: Malathion
Keywords: Water pollution
Keywords: Environmental Studies
Keywords: Environmental Monitoring
Keywords: Organophosphorus Compounds
Keywords: Malathion -- analysis
Keywords: Pesticides
Keywords: Water Pollution, Chemical -- statistics & numerical data
Keywords: Water Pollutants, Chemical
Keywords: Rivers -- chemistry
Keywords: Diazinon English. Copyright - Springer Science+Business Media, LLC 2012. Document feature - References. Last updated - 2013-02-24. DOI - 2646282121; 68847212; 108019; BVCX; 22349309; SPVLBVCX128886568. SubjectsTermNotLitGenreText - Iran. Abdel-Halim, K.Y.; Salama, A.K.; El-khateeb, E.N.; Bakry, N.M. Organophosphorus pollutants (OPP) in aquatic environment at Damietta Governorate, Egypt: Implications for monitoring and biomarker responses. Chemosphere, 63. 9 (2006): 1491-1498. Elsevier Ltd. American Public Health Association; Greenberg, A E. Standard methods for the examination of water and wastewater. Standard methods for the examination of water and wastewater. (1985). Ballesteros, E.; Parrado, M.J. Continuous solid-phase extraction and gas chromatographic determination of organophosphorus pesticides in natural and drinking waters. Journal of Chromatography A, 1029. 1-2 (2004): 267-273. Elsevier. Blomquist, Joel D; Denis, Janet M; Hetrick, James A; Jones, R David; et al. Pesticides in selected water-supply reservoirs and finished drinking water, 1999-2000; summary of results from a pilot monitoring program. Open-File Report - U. S. Geological Survey (2001): 65. U. S. Geological Survey. Castilho, JAA; Fenzl, N; Guillen, S M; Nascimento, F S. Organochlorine and organophosphorus pesticide residues in the Atoya river basin, Chinandega, Nicaragua. ENVIRONMENTAL POLLUTION, 110. 3 (2000): 523-533. ELSEVIER SCI LTD. Eichelberger, J W; Lichtenberg, J J. PERSISTENCE OF PESTICIDES IN RIVER WATER. Environmental Science and Technology, 5. 6 (1971): 541-544. Farajzadeh, Mir Ali; Seyedi, Seyed Esmaeil; Shalamzari, Mohammad Safi; Bamorowat, Mehdi. Dispersive liquid-liquid microextraction using extraction solvent lighter than water. JOURNAL OF SEPARATION SCIENCE, 32. 18 (2009): 3191-3200. WILEY-V C H VERLAG GMBH. GILLIOM, Robert J. PESTICIDES in U.S. streams and groundwater. Environmental science & technology, 41. 10 (2007): 3408-3414. American Chemical Society. Hela, Dimitra G.; Lambropoulou, Dimitra A.; Konstantinou, Ioannis K.; Albanis, Triantafyllos A. Environmental monitoring and ecological risk assessment for pesticide contamination and effects in Lake Pamvotis, northwestern Greece. Environmental Toxicology and Chemistry, 24. 6 (2005): 1548-1556. SETAC Press. HOFFMAN, R. S.; CAPEL, P. D.; LARSON, S. J. Comparison of pesticides in eight U.S. urban streams. Environmental toxicology and chemistry, 19. 9 (2000): 2249-2258. SETAC. Howard, PH; Howard, PH. Handbook of Environmental Fate and Exposure of Organic Chemicals. Volume I. Large Production and Priority Pollutants. (1989): LEWIS PUBLISHERS, INC., 121 SOUTH MAIN STREET, P.O. DRAWER 519, CHELSEA, MI 48118 (USA). Na, Ta; Fang, Zhou; Zhanqi, Gao; Ming, Zhong; et al. The status of pesticide residues in the drinking water sources in Meiliangwan Bay, Taihu Lake of China. ENVIRONMENTAL MONITORING AND ASSESSMENT, 123. 1-3 (2006): 351-370. SPRINGER. Newhart K (2006) Environmental fate of malathion. California Environmental Protection Agency, Department of Pesticide Regulation, Environmental Monitoring Branch, Sacramento. Pandey GN, Carney GC (1992) Environmental engineering. Tata McGraw Hill Publishing Company Limited, New Delhi. PEDERSEN, Joel A.; YEAGER, Matt A.; SUFFET, I. H. Organophosphorus insecticides in agricultural and residential runoff : Field observations and implications for total maximum daily load development. Environmental science & technology, 40. 7 (2006): 2120-2127. American Chemical Society. Real, Francisco J.; Benitez, F. Javier; Acero, Juan L.; Gonzalez, Manuel. Removal of diazinon by various advanced oxidation processes. Journal of Chemical Technology and Biotechnology, 82. 6 (2007): 566-574. John Wiley and Sons Ltd. Shayeghi, M., S.J. Shahtaheri and M. Selsele, 2001. Phosphorous insecticides residues in Mazandaran River Waters, Iran. Iran. J. Public. Health, 30: 115-118. Sun, Q.; Zhu, L.; Dong, M. Risk assessment of organic pesticides pollution in surface water of Hangzhou. ENVIRONMENTAL MONITORING AND ASSESSMENT, 117. 1-3 (2006): 377-385. SPRINGER. Tsuda, T.; Nakamura, T.; Inoue, A.; Tanaka, K. Pesticides in Water and Sediment from Littoral Area of Lake Biwa. BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 82. 6 (2009): 683-689. SPRINGER. Wilson, P. Chris; Foos, Jane Ferguson. Survey of carbamate and organophosphorous pesticide export from a South Florida (USA) agricultural watershed: Implications of sampling frequency on ecological risk estimation. Environmental Toxicology and Chemistry, 25. 11 (2006): 2847-2852. SETAC Press. Zhang, Yanming; Pagilla, Krishna. Treatment of malathion pesticide wastewater with nanofiltration and photo-Fenton oxidation. Desalination, 263. 1-3 (2010): 36-44. Elsevier

216. Falcon, L. A. Biological Factors that Affect the Success of Microbial Insecticides: Development of Integrated Control. 1973; 217, 173-186.


Rec #: 1470
Keywords: REFS CHECKED,REVIEW
Call Number: NO REFS CHECKED (CBL,DCTP,MLN), NO REVIEW (CBL,DCTP,MLN)
Notes: Chemical of Concern: CBL,DCTP,DDT,MLN,TXP

217. Fallico, B.; D'Urso, M. G., and Chiappara, E. Exposure to pesticides residues from consumption of Italian blood oranges. 2009; 26, 1024-1032.


Rec #: 13090
Keywords: CHEM METHODS
Notes: Chemical of Concern: MLN
Abstract: Abstract: This paper reports the results of a 5-year study to evaluate pesticide levels, derived from orchard activities, on Italy's most common orange cultivar (Citrus sinensis, L. Osbeck, cv. Tarocco). Using a Bayesian approach, the study allowed both the qualitative (number) and quantitative distributions (amount) of pesticides to be determined with its own probability value. Multi-residue analyses of 460 samples highlighted the presence of ethyl and methyl chlorpyrifos, dicofol, etofenprox, fenazaquin, fenitrothion, imazalil, malathion and metalaxil-m. A total of 30.5% of samples contained just one pesticide, 2.16% two pesticides and 0.65% of samples had three pesticides present simultaneously. The most common residue was ethyl chlorpyrifos followed by methyl chlorpyrifos. Estimated daily intake (EDI) values for ethyl and methyl chlorpyrifos, as well as the distance from the safety level (non-observed adverse effect level, NOAEL), were calculated. The risk was differentiated (1) to take account of the period of actual citrus consumption (180 days) and (2) to discriminate the risk derived from eating oranges containing a certain level of chlorpyrifos from unspecified pesticides. The most likely EDI values for ethyl chlorpyrifos derived from Italian blood orange consumption are 0.01 and 0.006 mg/day calculated for 180 and 365 days, respectively. Considering the probability of the occurrence of ethyl chlorpyrifos, these EDI values are reduced to 2.6 x 10(-3) and 1.3 x 10(-3) mg/day, respectively. For methyl chlorpyrifos, the most likely EDI values are 0.09 and 0.04 mg/day, respectively; considering the probability of its occurrence, the EDI values decrease to 6.7 x 10(-3) and 3.4 x 10(-3) mg/day, respectively. The results confirmed that levels of pesticides in Italian Tarocco oranges derived from a known controlled chain of production are safe.
Number of Volumes: 7
ISI Document Delivery No.: 457ZW ://CCC:000266979700008

218. Fan, Siqi and Zhang, Minghua. Pesticides Used on Walnuts in California: Use Patterns and Potential Impacts on Surface Water. 2012.


Rec #: 7960
Keywords: FATE
Notes: Chemical of Concern: MLN
Abstract: Abstract: Walnuts are an important specialty crop in California. In 2010, they reached a production of 503,000 tons which accounted for 99% of national production, and created profits over one billion dollars statewide. The major regions growing walnuts in California include the Sacramento Basin, San Joaquin Basin and Tulare Lake Basin. To maximize crop production, a large amount of pesticides was applied to control pests: The amount of active ingredient (AI) used in pesticide products exceeded 1000 tons annually in 1995-2009, which could have posed potential pollution to surface water. This study looked into both pesticide use and its potential impact on surface water from 1995 to 2009 on California walnuts, focusing on the pesticide categories of fungicides, insecticides and herbicides. A pesticide risk evaluation model, Pesticide Use Risk Evaluation (PURE), was applied in this study to quantitatively analyze potential impact of pesticide use on surface water. Results showed that among the three main basins, the Sacramento Basin had the highest fungicide risk intensity on surface water (annual average value: 978.25 R/ha, 42% and 358% higher than San Joaquin and Tulare Lake), due to a heavy use of copper hydroxide and maneb. San Joaquin had the highest insecticide risk intensity (973.73 R/ha, 33% and 56% higher than the Sacramento Basin and Tulare Lake) resulting mainly from chlorpyrifos, azinphos-methyl, chloropicrin, and malathion use. Herbicide showed a consistent low risk intensity (<50 R/ha) in all basins. The Mann-Kendall test showed fungicide and insecticide risk intensity presented a consistently decreasing trend in all basins, while herbicide risk intensity presented an increasing trend in Tulare Lake. A finer spatial scale analysis was conducted at township level (6Ă—6 mile 2 ) to assess the use and risk patterns in more details, the results of which are presented as GIS maps. Finally, based on some lab experiments observing pyrethroid use can cause mite outbreaks, a case study was carried out to examine the relationship between pyrethroid and miticide use on California walnuts and their potential impact on surface water. A developed model captured the relationship as the miticide use intensity is positively correlated with pyrethroid use intensity until it reaches a maximum value. Through a comprehensive pesticide use and risk analysis on California walnut, important conclusions are made. For example, pesticides such as copper hydroxide and chlorpyrifos have high toxicity in surface water. Our analysis indicates that if they were replaced by more environmentally benign pesticides - such as kaolin and petroleum oil - the overall risk scores and environmental impacts would decrease. These results can be useful to help local walnut growers make decisions on pesticide choices, and help regulators to make suggestions and integrated pesticide management on critical regions.
Start Page: 124
ISSN/ISBN: 9781267758798
Keywords: Agriculture
Keywords: Pesticide
Keywords: California walnut
Keywords: 0388:Hydrologic sciences
Keywords: Surface water
Keywords: 0595:Water Resource Management
Keywords: Gis
Keywords: Ipm
Keywords: 0473:Agriculture
Keywords: Water Resource Management
Keywords: Biological sciences
Keywords: Earth sciences
Keywords: Pesticide risk model
Keywords: Hydrologic sciences English. Copyright - Copyright ProQuest, UMI Dissertations Publishing 2012. Last updated - 2013-05-07. DOI - 2828805621; 70145852; 66569; 9781267758798; 1529960. First page - n/a

219. Farghaly, M. and El-Maghraby, S. Investigation of chronic toxicity of (14)C-fenitrothion and its degradation products on stored soybeans. 2009; 27, 1-6.


Rec #: 13110
Keywords: FOOD
Notes: Chemical of Concern: MLN
Abstract: Abstract: Grains of soybeans were treated with the recommended dose of fenitrothion insecticide, 5 mg/kg, and double that dose, before storage for 30 weeks under ambient local conditions. During the storage period. the penetration and distribution of insecticide residues were studied. The amount of surface residues on stored soybeans, internal extractable and bound residues were determined. Surface residues were found to decrease with the increase in time of storage, whereas internal residues showed a gradual increase with time to reach 56%, 54% of applied doses after 30 weeks. The amount of bound residues inside the matrix showed a slow increase with time. Toxicity of the total internal residues of fenitrothion in stored soybeans was studied in mice through a sub-chronic feeding experiment for 3 months. The maximum inhibition in plasma and erythrocyte cholinesterase activity was 37% and 13% after the first month, respectively. Treated mice suffered from deterioration of hepatic and renal functions as indicated by the increase level of blood serum esterase's and blood urea nitrogen. Percentage increase in alanine aminotransferase (ALT) and aspartate aminotransferase (AST) was reached to about 62% and 55%, respectively as compared with control animals with the end of feeding period. (C) 2008 Elsevier B.V. All rights reserved.
Number of Volumes: 1
ISI Document Delivery No.: 396AM ://CCC:000262564600001

220. Farnebo, S.; Zettersten, E. K.; Samuelsson, A.; Tesselaar, E., and Sjoberg, F. Assessment of Blood Flow Changes in Human Skin by Microdialysis Urea Clearance. 2011; 18, 198-204.


Rec #: 13120
Keywords: HUMAN HEALTH
Notes: Chemical of Concern: MLN
Abstract: Abstract: P>Objective: The aim of this study was to evaluate the urea clearance technique for the measurement of drug-induced blood flow changes in human skin and compare it to two non-invasive techniques: polarization light spectroscopy and laser Doppler perfusion imaging. Methods: Fifteen microdialysis catheters were placed intracutaneously on the volar aspect of the forearms of healthy human subjects and were perfused with nitroglycerine, noradrenaline, and again nitroglycerine to induce local tissue hyperemia, hypoperfusion, and hyperemia, respectively. Results: Urea clearance, but not the other techniques, detected the changes in blood flow during changes in flow. The last hyperemic response was detected by all three methods. Conclusion: Urea clearance can be used as a relatively simple method to estimate blood flow changes during microdialysis of vasoactive substances, in particular when the tissue is preconditioned in order to enhance the contrast between baseline and the responses to the provocations. Our results support that, in the model described, urea clearance was superior to the optical methods as it detected both the increases and decrease in blood flow, and the returns to baseline between these periods.
Number of Volumes: 3
ISI Document Delivery No.: 739ZD ://CCC:000288759900004

221. Fathi, Farkhondeh; Lagugnă©-Labarthet, Frană Ois; Pedersen, David B, and Kraatz, Heinz-Bernhard. Studies of the Interaction of Two Organophosphonates With Nanostructured Silver Surfaces. 2012 Oct 7; 137 , (19): 4448-4453.


Rec #: 5610
Keywords: CHEM METHODS
Notes: Chemical of Concern: MLN
Abstract: Abstract: Electrochemical cycling of silver surfaces in the presence of the organophosphonates paraoxon and malathion leads to changes in the electrochemical response of silver and the formation of silver nanostructures. Adsorption of the organophosphonates onto the silver surfaces causes a significant reduction in the observed current response due to an increase in the charge transfer resistance. Surface enhanced Raman spectroscopy (SERS) measurements indicate that paraoxon adsorbs with no structural changes, while malathion decomposes and a thiophosphonate interacts with the surface. The SERS study of these adsorbates was carried out by changing the electrochemical conditions and the concentration of the organophosphonates. The size of the nanostructures greatly influences the SERS signal and it is observed that the strongest enhancement is observed for mid-sized nanostructures with a uniform thickness on the surface. The limit of detection was shown to be in the range of 10 nM to 10 pM for paraoxon and malathion, respectively. eng. Date completed - 2013-01-17. Date created - 2012-08-29. Date revised - 2013-01-25. Last updated - 2013-01-25. DOI - MEDL-22866328; 22866328; 1364-5528

222. Faust, D. R.; Knowles, N.; Magruder, E.; Haukos, D. A.; Cobb, G. P.; Maul, J. D.; Anderson, T. A., and Smith, P. N. Inorganic and organic contaminants in sediments from an urban playa and associated toxicity among Hyalella azteca. 2012; 94, 1746-1757.


Rec #: 13140
Keywords: SEDIMENT CONC
Notes: Chemical of Concern: MLN
Abstract: Abstract: Playa wetlands are important components of the Southern High Plains (USA) landscape as they are the major aquatic surface feature. Chemical contaminants associated with playas have been documented, particularly for grassland and agricultural watersheds, but not for playas in urban settings. The objectives of this study were to determine concentrations of inorganic and organic contaminants in sediments from an urban playa within the I-20 Wildlife Preserve and Jenna Welch Nature Study Center in Midland, TX, and evaluate toxicity of these sediments to Hyalella azteca. Concentrations of most trace elements were below sediment quality guidelines with exceptions of lead, cadmium, and arsenic. Concentrations of organic contaminants, particularly PAHs, DDT, DDE, and malathion, were above sediment quality guidelines at various locations within the playa. Decreased survival was observed among H. azteca exposed to sediment from a single location when compared those exposed to reference sediments. This location also produced maximum observed concentrations for five of seven trace elements, potentially due to its location at the lowest elevation within the playa. This study documented concentrations of contaminants in sediments of an urban playa associated with past and present land uses in its urban setting, including those from automotive emissions and historical pesticide use.
Number of Volumes: 9
ISI Document Delivery No.: 026VP ://CCC:000310311500011

223. Faust, S. D. and Gomaa, H. M. Chemical Hydrolysis of Some Organic Phosphorus and Carbamate Pesticides in Aquatic Environments. 1972; 3, (3): 171-201.


Rec #: 550
Keywords: REFS CHECKED,REVIEW
Call Number: NO REFS CHECKED (AZ,DCTP,DDVP,DMT,DS,DZ,FNT,MLN,MP,MVP,OXD,PRT,TCF), NO REVIEW (AZ,DCTP,DDVP,DMT,DS,DZ,FNT,MLN,MP,MVP,OXD,PRT,TCF)
Notes: Chemical of Concern: AZ,DCTP,DDVP,DMT,DS,DZ,EPRN,ETN,FNT,FNTH,MLN,MP,MVP,OXD,PPHD,PRN,PRT,TCF

224. Fedorenkova, A.; Vonk, J. A.; Lenders, H. J. R.; Creemers, R. C. M.; Breure, A. M., and Hendriks, A. J. Ranking Ecological Risks of Multiple Chemical Stressors on Amphibians. 2012; 31, (6): 1416-1421.


Rec #: 1680
Keywords: MODELING,REFS CHECKED
Call Number: NO MODELING (ACR,ATZ,AZ,CBD,CBF,CBL,Cu,DM,DU,DZ,ES,MLN,MP,PMR), NO REFS CHECKED (ACR,ATZ,AZ,CBD,CBF,CBL,Cu,DM,DU,DZ,ES,MLN,MP,PMR)
Notes: Chemical of Concern: ACR,ATZ,CBD,CBF,CBL,Cu,DDT,DLD,DM,DU,DZ,EN,EPRN,ES,HCCH,MLN,MP,NH4,NO3,PMR,PPCP,PRN

225. Fenoll, J.; Hellin, P.; Martinez, C. M.; Miguel, M., and Flores, P. Multiresidue Method for Analysis of Pesticides in Pepper and Tomato by Gas Chromatography with Nitrogen-Phosphorus Detection. Departamento de Calidad y Garantia Alimentaria, C/Mayor s/n,IMIDA, Murcia, Spain////: SOIL; 2007; 105, (2): 711-719.


Rec #: 1200
Keywords: NO DURATION
Call Number: NO DURATION (AZX,CPY,CPYM,CYF,CYP,Conazoles,DM,DZ,GCYH,MLN,OXF,PDM,PIRM,PRB,PZM,TAUF,TDF)
Notes: Chemical of Concern: AZX,BPZ,CPY,CPYM,CYD,CYF,CYP,CYPM,DF,DM,DZ,FDX,GCYH,KRSM,MLN,OXF,PDM,PHSL,PIM,PIRM,PRB,PYX,PZM,TAUF,TCM,TDF,TDM,TEZ,TYF

226. Fenoll, Jose; Ruiz, Encarnacion; Flores, Pilar; Hellin, Pilar; Navarro, Simon, and Fenoll, Jose. Reduction of the Movement and Persistence of Pesticides in Soil Through Common Agronomic Practices. 2011 Nov; 85, (8): 1375-1382.


Rec #: 3050
Keywords: FATE
Notes: Chemical of Concern: MLN
Abstract: Abstract: Laboratory and field studies were conducted in order to determine the leaching potential of eight pesticides commonly used during pepper cultivation by use of disturbed soil columns and field lysimeters, respectively. Two soils with different organic matter content (soils A and B) were used. Additionally, soil B was amended with compost (sheep manure). The tested compounds were cypermethrin, chlorpyrifos-methyl, bifenthrin, chlorpyrifos, cyfluthrin, endosulfan, malathion and tolclofos-methyl. In soil B (lower organic matter content), only endosulfan sulphate, malathion and tolclofos-methyl were found in leachates. For the soil A (higher organic matter content) and amended soil B, pesticide residues were not found in the leachates. In addition, this paper reports on the use of common agronomic practices (solarization and biosolarization) to enhance degradation of these pesticides from polluted soil A. The results showed that both solarization and biosolarization enhanced the degradation rates of endosulfan, bifenthrin and tolclofos-methyl compared with the control. Most of the studied pesticides showed similar behavior under solarization and biosolarization conditions. However, chlorpyrifos was degraded to a greater extent in the solarization than in biosolarization treatment. The results obtained point to the interest in the use of organic amendment in reducing the pollution of groundwater by pesticide drainage and in the use of solarization and biosolarization in reducing the persistence of pesticides in soil.
Keywords: Sulfates
Keywords: Degradation
Keywords: ENA 09:Land Use & Planning
Keywords: Organic matter
Keywords: P 2000:FRESHWATER POLLUTION
Keywords: Malathion
Keywords: Environmental Studies
Keywords: Endosulfan
Keywords: Soil
Keywords: Chlorpyrifos
Keywords: Pesticides
Keywords: Environment Abstracts; Pollution Abstracts
Keywords: Leachates English. Date revised - 2012-01-01. Last updated - 2012-01-26. DOI - OB-0055fb49-d6c3-48f0-9698csamfg201; 16058870; 0045-6535. SubjectsTermNotLitGenreText - Sulfates; Chlorpyrifos; Soil; Degradation; Organic matter; Pesticides; Leachates; Malathion; Endosulfan

227. Ferguson, D. E. Characteristics and Significance of Resistance to Insecticides in Fishes. 5003//: 1968: 531-536.


Rec #: 1010
Keywords: REFS CHECKED,REVIEW
Call Number: NO REFS CHECKED (AMSV,CPY,DCF,MLN,MP,TEPP), NO REVIEW (AMSV,CPY,DCF,MLN,MP,TEPP)
Notes: Chemical of Concern: AMSV,CHD,CPY,DCF,DDE,DDT,EN,MLN,MP,MXC,TEPP,TXP

228. Fernandes, Virginia C; Domingues, Valentina F; Mateus, Nuno; Delerue-Matos, Cristina, and Fernandes, Virginia C. Pesticide Residues in Portuguese Strawberries Grown in 2009-2010 Using Integrated Pest Management and Organic Farming. 2012 Nov; 19, (9): 4184-4192.


Rec #: 2450
Keywords: CHEM METHODS
Notes: Chemical of Concern: MLN
Abstract: Abstract: Pesticides are among the most widely used chemicals in the world. Because of the widespread use of agricultural chemicals in food production, people are exposed to low levels of pesticide residues through their diets. Scientists do not yet have a total understanding of the health effects of these pesticide residues. This work aims to determine differences in terms of pesticide residue content in Portuguese strawberries grown using different agriculture practices. The Quick, Easy, Cheap, Effective, Rugged, and Safe sample preparation method was conducted and shown to have good performance for multiclass pesticides extraction in strawberries. The screening of 25 pesticides residue was performed by gas chromatography-tandem mass spectrometry. In quantitative validation, acceptable performances were achieved with recoveries of 70-120 and <12 % residual standard deviation for 25 pesticides. Good linearity was obtained for all the target compounds, with highly satisfactory repeatability. The limits of detection were in the range of 0.1-28 mu g/kg. The method was applied to analyze strawberry samples from organic and integrated pest management (IPM) practices harvested in 2009-2010. The results showed the presence of fludioxonil, bifenthrin, mepanipyrim, tolylfluanid, cyprodinil, tetraconazole, and malathion when using IPM below the maximum residue levels.
Keywords: Diets
Keywords: Chemicals
Keywords: Agriculture
Keywords: Pesticide residues
Keywords: Food
Keywords: Mass spectrometry
Keywords: Pollution research
Keywords: Pest control
Keywords: Fragaria
Keywords: Organic farming
Keywords: Integrated pest management
Keywords: Mass spectroscopy
Keywords: Malathion
Keywords: ENA 06:Food & Drugs
Keywords: Fludioxonil
Keywords: Standard deviation
Keywords: P 9999:GENERAL POLLUTION
Keywords: Environmental Studies--Pollution
Keywords: Pesticides
Keywords: Pollution Abstracts; Toxicology Abstracts; Environment Abstracts
Keywords: Economics
Keywords: X 24330:Agrochemicals
Keywords: Food production English. Date revised - 2013-03-01. Last updated - 2013-03-21. DOI - OB-d726114d-aec3-4b2e-8d08mfgefd107; 17288572; 0944-1344; 1614-7499. SubjectsTermNotLitGenreText - Agriculture; Fludioxonil; Standard deviation; Pesticide residues; Food; Pesticides; Pollution research; Pest control; Malathion; Mass spectroscopy; Diets; Chemicals; Economics; Mass spectrometry; Organic farming; Integrated pest management; Food production; Fragaria

229. Fianko, Joseph R; Donkor, Augustine; Lowor, Samuel T; Yeboah, Philip O, and Fianko, Joseph R. Agrochemicals and the Ghanaian Environment, a Review. 2011 May; 2, (3): 221.


Rec #: 6410
Keywords: REVIEW
Notes: Chemical of Concern: MLN
Abstract: Abstract: Agrochemicals are generally recognized as a significant factor in enhancing the ability to meet Ghana's need for sufficient, safe and affordable food and fiber, however, increased usage have led to environmental deterioration. In Ghana agriculture and public health sectors remain the major contributors of pollutants into the environment. This is a systematic review of studies done in Ghana to give an integrated picture of agrochemicals especially pesticides exposure to humans, animals, plants, water, soil/sediment and atmosphere in Ghana. Although the widespread usage of agrochemicals in Ghana has contributed immensely to increased food supply and improvement in public health, it has caused tremendous harm to the environment. Water bodies, fish, vegetables, food, soil and sediment have been found to be pesticide contaminated. There is considerable evidence that farmers have overused agrochemicals especially pesticides. It is evident from biological monitoring studies that farmers are at higher risk for acute and chronic health effects associated with pesticides due to occupational exposure. Furthermore the intensive use of pesticides involves a special risk of for field workers, consumers and unacceptable residue levels in exportable products may serve as barrier to international trade. This review will set the future course of action of different studies on agrochemical usage and pesticide exposure in Ghana.
Keywords: Environmental Studies English. Date revised - 2011-07-01. Last updated - 2011-11-08. DOI - OB-9c1d6aac-1eac-467e-87cbmfgefd107; 15200983; 2152-2197; 2152-2219

230. Filho, Adalberto Menezes; Dos Santos, Fabio Neves; Pereira, Pedro Afonso De Paula, and Filho, Adalberto Menezes. Development, Validation and Application of a Methodology Based on Solid-Phase Micro Extraction Followed by Gas Chromatography Coupled to Mass Spectrometry (Spme/Gc-Ms) for the Determination of Pesticide Residues in Mangoes. 2010 Apr 15; 81, (1-2): 346-354.


Rec #: 7030
Keywords: CHEM METHODS
Notes: Chemical of Concern: MLN
Abstract: Abstract: A method was developed for the simultaneous analysis of 14 pesticide residues (clofentezine, carbofuran, diazinon, methyl parathion, malathion, fenthion, thiabendazole, imazalil, bifenthrin, permethrin, prochloraz, pyraclostrobin, difenoconazole and azoxystrobin) in mango fruit, based on solid-phase micro extraction (SPME) coupled to gas chromatography-mass spectrometry (GC-MS). Different parameters of the method were evaluated, such as fiber type, extraction mode (direct immersion and headspace), temperature, extraction and desorption times, stirring velocities and ionic strength. The best results were obtained using polyacrylate fiber and direct immersion mode at 50 degree C for 30 min, along with stirring at 250 rpm and desorption for 5 min at 280 degree C. The method was validated using mango samples spiked with pesticides at concentration levels ranging from 33.3 to 333.3 mu g kg super(-1). The average recoveries (n = 3) for the lowest concentration level ranged from 71.6 to 117.5%, with relative standard deviations between 3.1 and 12.3%, respectively. Detection and quantification limits ranged from 1.0 to 3.3 mu g kg super(-1) and from 3.33 to 33.33 mu g kg super(-1), respectively. The optimized method was then applied to 16 locally purchased mango samples, all of them containing the pesticides bifenthrin and azoxystrobin in concentrations of 18.3-57.4 and 12.7-55.8 mu g kg super(-1), respectively, although these values were below the MRL established by Brazilian legislation. The method proved to be selective, sensitive, and with good precision and recovery rates, presenting LOQ below the MRL admitted by Brazilian legislation.
Keywords: Pollution Abstracts English. Date revised - 2010-06-01. Last updated - 2011-12-14. DOI - 6fd72ff0-7c08-44ee-a027csamfg201; 12968827; 0039-9140

231. Fischer, J. E. Oral LD50 Study in Albino Rats with AC 6,601 Malathion Technical (Cheminova Production Batch). 1991.


Rec #: 560
Keywords: NO SOURCE
Call Number: NO SOURCE (MLN)
Notes: Chemical of Concern: MLN

232. Fjordbă¸Ge, Annika S; Baun, Anders; Vastrup, Troels, and Kjeldsen, Peter. Zero Valent Iron Reduces Toxicity and Concentrations of Organophosphate Pesticides in Contaminated Groundwater. 2013 Jan; 90, (2): 627-633.


Rec #: 5510
Keywords: MIXTURE
Notes: Chemical of Concern: MLN
Abstract: Abstract: The potential of zero valent iron (ZVI) for remediation of contaminated groundwater from an abandoned chemical disposal site was examined through batch and column experiments. The key contaminants were organophosphate pesticides but the chemical analysis also comprised additional 22 compounds including synthesis intermediates and degradation products of organophosphates. The ZVI treatment showed that all the contaminants were degraded with the exception of two diesters (phosphorothioates). The most rapid reduction was found for methyl parathion, ethyl parathion and malathion, which had first-order degradation rate constants on the order of 10(-3) min(-1).


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