Metal Application



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Table S1. Metals applications with primary substitutes and substitute performance

Metal

Application

Application Details

Percentage into Application

Primary Substitute

Substitute Performance

Analysis Details

Li

Batteries

Used in rechargeable batteries (i.e., lithium-ion and lithium polymer) and primary (disposable) lithium batteries (as the anode material)

25% (1) (global)


nickel-metal hydride batteries (rechargeable batteries substitute), and zinc for primary batteries (1)

good



Ceramics and glass

Reduces fusion temperatures, permits control of contaminant emissions, and produces a better quality product (2)

18% (1) (global)


sodium (1)

exemplary




Lubricating greases

Used in specialty lubricants and greases used for working in extreme temperature and change conditions (2)

12% (1) (global)


calcium (1, 3)

good




Pharmaceuticals and polymers

Used in pharmaceuticals (e.g., to treat bipolar disorder and as a catalyst in some new applications for weight control) and in polymers (2)

7% (1) (global)


none

not applicable




Air conditioning

Used in air conditioning and dehumidification systems

6% (1) (global)


ammonia/water systems (4)

poor




Primary aluminum production

Lowers the melting point of the cryolite bath in primary aluminum production (2)

4% (1) (global)


sodium (2)

good




Continuous casting

Addition of lithium to continuous casting mold fluxes provides thermal insulation and lubrication

3% (1) (global)


sodium

good




Other

Includes chemical processing

25% (1) (global)

not applicable

not applicable




Be

Computer and telecommunications products

Serves as both a structural support and heat sink in product applications such as computers, cellular phones, integrated circuits, and radars

50% (global)


copper-nickel-silicon alloys

adequate

Global values based on estimates for the United States, where the reference indicated nearly one-half was used in computers and telecommunications (1); computers and telecommunications were set at 50%, and the total into the other two applications was assumed to be divided equally

Aerospace and defense

Used in lightweight structural components

25% (global)


polymers

adequate

Global values based on estimates for the United States, where the reference indicated nearly one-half was used in computers and telecommunications (1); computers and telecommunications were set at 50%, and the total into the other two applications was assumed to be divided equally

Other

Includes appliances, automotive and medical applications, electronics, and industrial components

25% (global)


not applicable

not applicable

Global values based on estimates for the United States, where the reference indicated nearly one-half was used in computers and telecommunications (1); computers and telecommunications were set at 50%, and the total into the other two applications was assumed to be divided equally

B

Ceramics and glass

Used in borosilicate glass for laboratory glassware and consumer cookware and to form high-strength, lightweight materials used in aerospace and consumer applications

64% (5) (global)


sodium (1)

good

Percentages into applications at the global level do not sum to one hundred percent due to rounding

Soaps, detergents, and bleaches

Used primarily in household laundry and cleaning products

4% (5) (global)


chlorine (for bleaches) and enzymes (for soaps and detergents) (1)

good

Percentages into applications at the global level do not sum to one hundred percent due to rounding

Agriculture

Serves as a micronutrient

4% (5) (global)


none

not applicable

Percentages into applications at the global level do not sum to one hundred percent due to rounding

Other

Includes ferroboron, enamels, and glazes

27% (5) (global)


not applicable

not applicable

Percentages into applications at the global level do not sum to one hundred percent due to rounding

Mg

Refractories

Used as a refractory material in furnace linings for iron, steel, nonferrous metals, glass, and cement production

83% (6) (global)


none

not applicable

Global values are for 2002

Alumina, chromite, and silica substitute for magnesia in some refractory applications (1), but there is no single primary substitute



Environmental

Used in water treatment and stack-gas scrubbing

6% (6) (global)

lime

exemplary

Global values are for 2002


Agriculture

Serves as a micronutrient

5% (6) (global)

none

not applicable

Global values are for 2002


Other

Includes magnesium metal uses (e.g., in aluminum-based alloys used in packaging and transportation, structural uses, and desulfurization of iron and steel), welding fluxes, and chemicals

6% (6) (global)


not applicable

not applicable

Global values are for 2002


Al

Transportation

Widely used in automotive and truck, railroad, marine, and aerospace industries as castings, extrusions, and sheets

28% (7) (global)


steel

adequate

Global values are for 2007


Building and construction

Used in windows, doors, facades siding, gutters, and roofing

24% (7) (global)


steel

good

Global values are for 2007


Packaging

Used primarily in cans and foil

15% (7) (global)

steel

good

Global values are for 2007


Electrical

Used in electrical lines for power transmission and distribution

12% (7) (global)

copper

exemplary

Global values are for 2007


Machinery

Used in machinery tools, such as the mold material for the plastics industry

8% (7) (global)


steel

adequate

Global values are for 2007


Consumer durables

Includes use in cooking utensils and home appliances (e.g., refrigerators)

7% (7) (global)


copper

good

Global values are for 2007


Other

Includes use in applications like petrochemical piping and tanks

6% (7) (global)

not applicable

not applicable

Global values are for 2007


Sc

Aerospace and defense

Primarily used in aerospace and military vehicles (8, 9) as an alloying element with aluminum to provide strength and weldability (8, 10)

50% (informed estimate) (global)


aluminum itself, without addition of scandium

adequate




Lighting

Used in high-intensity metal halide lamps (11)

20% (informed estimate) (global)

none

not applicable




Sports equipment

Used primarily in bicycles, baseball bats, golf clubs, and lacrosse sticks (12)

20% (informed estimate) (global)


titanium

good




Other

Includes metallurgical research, analytical standards, capacitors, and transistors

10% (informed estimate) (global)

not applicable

not applicable




Ti

Pigments

Used in paint, plastics, ceramics, and paper

88% (global)


talc

adequate

Based upon the estimate that 95% of total titanium supply is consumed in the form of titanium dioxide (13) and, globally, that 93% of titanium dioxide is used as a white pigment in paint, plastic, and paper from TZ Minerals International as cited in (14)

Other

Includes titanium metal uses and chemicals

12% (global)


not applicable

not applicable




V

Full alloy steel

Used in castings and pipeline fittings

43% (global)


niobium (1, 15)

adequate

Global value is an aggregate category of “steel” (16) and was disaggregated based upon United States values (1)

High-strength low-alloy steel

Used in construction, pipelines, and automotive applications

32% (global)


niobium (1, 15)

adequate

Global value is an aggregate category of “steel” (16) and was disaggregated based upon United States values (1)

Carbon steel

Reinforces bars used mostly in the automobile industry and in construction

16% (global)


niobium (1, 15)

adequate

Global value is an aggregate category of “steel” (16) and was disaggregated based upon United States values (1)

Other

Includes use in batteries and jewelry

9% (global)


not applicable

not applicable




Cr

Buildings and infrastructure

Used in elevators, street furniture, and steel reinforced concrete

25% (17) (global)

manganese

adequate

Application is dominated by constructional alloys for which manganese, molybdenum, and nickel are considered adequate substitutes (18). Aluminum is an adequate substitute in elevators and street furniture. Galvanized steel is an adequate substitute in steel reinforced concrete.

Global values are for 2000



Industrial machinery

Used in chemical and petrochemical applications, as well as in power generation, food processing, heat exchangers, and tanks

25% (17) (global)

none

not applicable

Aluminum is a poor substitute in food processing equipment.

Global values are for 2000



Transportation

Used in cars, ships, trains, aircraft components, and bicycles

15% (17) (global)

aluminum

adequate

Aluminum is an adequate substitute for railway passenger cars, bicycles, and automotive catalysts. No substitutes exist for the transport of chemicals or food by truck, rail, or ship, or for the hulls of container ships or bulk carriers. Tin-nickel, silicon-based coatings, and organic polymer films are adequate substitutes for automotive plating applications.

Global values are for 2000



Household appliances and electronics

Used in dishwashers, washing machines, and consumer electronics

5% (17) (global)

aluminum

adequate

Aluminum and plastic are good substitutes in white goods. Tin-nickel alloy is an adequate substitute for plating in electronics.

Global values are for 2000




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